HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydroquinone → 3-(p-Tolyl)acrylaldehyde
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydroquinone | HCID 785 | — |
| Reactant | 3-(4-Methylphenyl)prop-2-yn-1-ol | HCID 589715 | — |
| Solvent | Formic Acid | HCID 284 | — |
| Product | 3-(p-Tolyl)acrylaldehyde | HCID 582941 | 80% |
Reaction Steps
A mixture of 250 g of 75% strength aqueous formic acid, 50 g of p-methylphenylethynylcarbinol and 0.5 g of hydroquinone is refluxed for 1 hour and then worked up as described in Example 1 to give 40 g (corresponding to 80% of theory) of p-methylcinnamaldehyde having a boiling point of 90°-95° C./0.1 mbar.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04996365 |
| Source dataset | uspto-grants-1991_02 |
| ORD ID | ord-a740dbf13ca54fe3b35ce19d13a20f02 |
| Source note | uspto-grants-1991_02 |