HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbazole → 9-Dodecyl-9H-carbazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbazole | HCID 6854 | — |
| Reactant | 1-Bromododecane | HCID 8919 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | 9-Heptyl-9H-carbazole | HCID 13860482 | — |
| Catalyst | Benzyl triethylammonium chloride | HCID 66133 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | 9-Dodecyl-9H-carbazole | HCID 12338626 | — |
Reaction Steps
N-Dodecyl carbazole was prepared from carbazole (66 g, 0.40 mol), 1-bromododecane (100 g, 0.41 mol, commercially available from Aldrich, Milwaukee, Wis.), benzyltriethyl ammonium chloride (4.48 g, 0.02 mol), toluene (400 ml), and sodium hydroxide (200 g of 50% aqueous solution) according to the procedure described for N-heptylcarbazole
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06864025B2 |
| Source dataset | uspto-grants-2005_03 |
| ORD ID | ord-6f3418e5b147442d8e7249c705956551 |
| Source note | uspto-grants-2005_03 |