HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbazole → N-Tridecylcarbazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbazole | HCID 6854 | — |
| Reactant | 1-Bromotridecane | HCID 13000 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | 9-Heptyl-9H-carbazole | HCID 13860482 | — |
| Catalyst | Benzyl triethylammonium chloride | HCID 66133 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | N-Tridecylcarbazole | HCID 13860485 | — |
Reaction Steps
N-Tridecylcarbazole was prepared from carbazole (62.43 g, 0.37 mol), 1-bromotridecane (100 g, 0.38 mol, commercially available from Aldrich, Milwaukee, Wis.), benzyltriethyl ammonium chloride (4.24 g. 0.018 mol), toluene (400 ml), and 50% aqueous NaOH (200 g) according to the procedure described for N-heptylcarbazole. The product was obtained as 120 g of brown liquid (96% yield).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06864025B2 |
| Source dataset | uspto-grants-2005_03 |
| ORD ID | ord-2a13379a07cd4fe6acc78fb5c80c72b3 |
| Source note | uspto-grants-2005_03 |