HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbazole → N-Propylphenylcarbazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbazole | HCID 6854 | — |
| Reactant | (3-Bromopropyl)benzene | HCID 12503 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | 9-Heptyl-9H-carbazole | HCID 13860482 | — |
| Catalyst | Benzyl triethylammonium chloride | HCID 66133 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | N-Propylphenylcarbazole | HCID 69731188 | — |
Reaction Steps
N-Propylphenylcarbazole was prepared from carbazole (82.18 g, 0.49 ml), 1-bromo-3-phenylpropane (100 g, 0.50 mol, commercially available from Aldrich, Milwaukee, Wis.), benzyltriethyl ammonium chloride (5.58 g, 0.025 mol), toluene (400 ml), and 50% aqueous NaOH (200 g) according to the procedure described for N-heptylcarbazole. 108 g of the product was obtained as a white solid (77% yield).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06864025B2 |
| Source dataset | uspto-grants-2005_03 |
| ORD ID | ord-b3bafcb236124613912294b73d6217e3 |
| Source note | uspto-grants-2005_03 |