HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbazole → N-2-Ethylhexylcarbazole
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbazole | HCID 6854 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | 2-Ethylhexyl bromide | HCID 86804 | — |
| Reactant | 9-Heptyl-9H-carbazole | HCID 13860482 | — |
| Catalyst | Benzyl triethylammonium chloride | HCID 66133 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | N-2-Ethylhexylcarbazole | HCID 66872719 | — |
Reaction Steps
N-2-Ethylhexylcarbazole was prepared from carbazole (85.09 g, 0.51 mol), 2-ethylhexylbromide (100 g, 0.52 mol, commercially available from Aldrich, Milwaukee, Wis.), benzyltriethyl ammonium chloride (5.78 g, 0.025 mol), toluene (400 ml), and 50% aqueous NaOH solution (200 g) according to the procedure described for N-heptylcarbazole. The product was obtained as 115 g of brownish liquid (81% yield).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06864025B2 |
| Source dataset | uspto-grants-2005_03 |
| ORD ID | ord-9fbf4fceb2d94378bc29d0bf9621c2d9 |
| Source note | uspto-grants-2005_03 |