HuagongsheHuagongshe Chemistry Print Report · For research reference only
m-Chloroperbenzoic acid → (+/-)-1-(Oxiranylmethyl)-2,4-imidazolidinedione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Reactant | Bisulfite | HCID 104748 | — |
| Reactant | 1-(Prop-2-en-1-yl)imidazolidine-2,4-dione | HCID 22020924 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | (+/-)-1-(Oxiranylmethyl)-2,4-imidazolidinedione | HCID 22020929 | 89% |
Reaction Steps
A reaction solution of 1-(2-propenyl)-2,4-imidazolidinedione (0.036 mol) and 3-chlorobenzenecarboperoxoic acid (0.043 mol, 70.75%) in DCM (25 ml) was stirred for 2 hours at room temperature. An aqueous solution of bisulfite was added (to remove excess 3-chlorobenzenecarboperoxoic acid) and the mixture was stirred for 10 minutes. Na2CO3 was added and this mixture was extracted with DCM. The separated organic layer was dried, filtered and the solvent evaporated, yielding 5 g (89%) of (±)-1-(oxiranylmethyl)-2,4-imidazolidinedione (interm. 1).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06864273B1 |
| Source dataset | uspto-grants-2005_03 |
| ORD ID | ord-d18fdd7c2414498fb2c7566b05e5f192 |
| Source note | uspto-grants-2005_03 |