HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methanol → HCID 86594184, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methanol | HCID 887 | — |
| Reactant | 4-methoxybenzyl (1R,3aR,4S,8aS)-6-chloro-4-formyl-3-isopropyl-8a-{[(4-methoxybenzyl)oxy]methyl}-7-methyl-4,4a,5,6,7,7a,8,8a-octahydro-1,4-methano-s-indacene-3a(1H)-carboxylate | HCID 86594185 | — |
| Catalyst | Palladium hydroxide | HCID 9942167 | — |
| Product | HCID 86594184 | HCID 86594184 | — |
Reaction Steps
To a solution of 40 (40 mg, 0.066 mmol) in CH3OH (5 mL) was added Pearlman's catalyst (10 mg). The mixture was stirred under hydrogen (balloon pressure) for about 15 minutes. After filtration and concentration in vacuo, about 23.7 mg of 41 was obtained and used directly in the next step.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06864278B2 |
| Source dataset | uspto-grants-2005_03 |
| ORD ID | ord-cc0564c27a73409f850c405507afd9da |
| Source note | uspto-grants-2005_03 |