Ethylene → ethylene/propylene VNB
Reaction equation
C=C.[CH2:3]=[CH:4]C.[CH:6]([CH:8]1[CH2:13][CH:12]2[CH2:14][CH:9]1[CH:10]=[CH:11]2)=[CH2:7].[H][H].[Al](Cl)(CC)CC>CCCCCC>[CH2:3]=[CH2:4].[CH2:7]=[CH:6][CH3:8].[CH:6]([CH:8]1[CH2:13][CH:12]2[CH2:14][CH:9]1[CH:10]=[CH:11]2)=[CH2:7]Participants
7
Reactant 5
Product 1
Reagents, catalysts & solvents 1
Procedure
In a 100-liter stainless steel polymerization reactor equipped with a stirring blade (number of stirring revolutions: 250 rpm), terpolymerization of ethylene, propylene and 5-vinyl-2-norbornene was continuously carried out. To the liquid phase in the reactor were fed hexane at a rate of 60 l/hr, ethylene at a rate of 3.7 kg/hr, propylene at a rate of 8.0 kg/hr and 5-vinyl-2-norbornene at a rate of 480 g/hr, and were further continuously fed hydrogen at a rate of 50 l/hr and as catalysts VOCl3 at a rate of 48 mmol/hr, Al(Et)2Cl at a rate of 240 mmol/hr and Al(Et)1.5Cl1.5 at a rate of 48 mmol/hr, through the side inlet of the reactor.
Sources & evidence
- ORD record
- ord-5021612d7b2d4cffbe353a4588ed1fb5
- Source dataset
- uspto-grants-2005_03
- Patent number
- US06864315B1
Reaction notes
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