HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzyl Alcohol → 2-(Benzyloxy)benzyl-triphenylphosphonium bromide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzyl Alcohol | HCID 244 | — |
| Reactant | Triphenylphosphonium hydrobromide | HCID 22178555 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | 2-(Benzyloxy)benzyl-triphenylphosphonium bromide | HCID 11410109 | — |
Reaction Steps
15.15 g (70.7 mmol) of the benzyl alcohol IIIa and 21.86 g (63.7 mmol) of triphenyl-phosphonium hydrobromide in 240 ml of acetonitrile are heated at reflux for 5 hours. The solvent is evaporated under reduced pressure, and diethyl ether is then added. The solid is filtered and dried under reduced pressure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06864287B1 |
| Source dataset | uspto-grants-2005_03 |
| ORD ID | ord-386711396fe54941b2746e6a44162c3f |
| Source note | uspto-grants-2005_03 |