HuagongsheHuagongshe Chemistry Print Report · For research reference only
2,5-Bis(4-(3,5,5-trimethylhexyl)benzoyl)terephthalic acid → 2,5-Bis[4-(3,5,5-trimethylhexyl)benzyl]terephthalic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2,5-Bis(4-(3,5,5-trimethylhexyl)benzoyl)terephthalic acid | HCID 22269437 | — |
| Reactant | HCID 178418361 | HCID 178418361 | — |
| Catalyst | Palladium | HCID 23938 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 2,5-Bis[4-(3,5,5-trimethylhexyl)benzyl]terephthalic acid | HCID 22269452 | — |
Reaction Steps
A mixture containing 20.0 grams of 2,5-bis[4-(3,5,5-trimethylhexyl)benzoyl]terephthalic acid in 1500 mL of tetrahydrofuran (THF) and 1.4 grams of 10% palladium on carbon (as a catalyst) was heated to 90° C. in an atmosphere of hydrogen at 620 kPa and 90° C. for 17 hours. The mixture was filtered through Celite™ diatomaceous earth filter agent to remove the catalyst. The filtrate was concentrated in vacuo to give 2,5-bis[4-(3,5,5-trimethylhexyl)benzyl]terephthalic acid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06864396B2 |
| Source dataset | uspto-grants-2005_03 |
| ORD ID | ord-efb7cce3b95c4f64bc29caebd5a90cde |
| Source note | uspto-grants-2005_03 |