HRID984339

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID9816147

Ethyl (2S)-2-ethoxy-3-(4-hydroxyphenyl)propanoate

C13H18O4

$结构：C/C(=C\CO)c1ccc(-c2cccc(-c3ccccc3)c2)cc1$

HCID20765800

未命名化合物

PRODUCTS

生成物

$结构：CCOC(=O)[C@H](Cc1ccc(OC/C=C(\C)c2ccc(-c3cccc(-c4ccccc4)c3)cc2)cc1)OCC$

HCID20765808

未命名化合物

收率 80%

PROCEDURE

实验过程

The title compound (0.41 g, 80% yield) was prepared from (E)-3-[1,1′;3′,1″]terphenyl-4″-yl-but-2-en-1-ol (0.30 g, 1.0 mmol) and (S)-ethyl 2-ethoxy-3-(4-hydroxyphenyl)-propionate (0.25 g, 1.05 mmol) by a procedure analogous to that described in example 52 c.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-473262b99082486297240b3d97f371f8
来源数据集: uspto-grants-2005_03
DOI: 10.6084/m9.figshare.5104873.v1
专利: US06867218B2
来源说明: uspto-grants-2005_03

反应 SMILES

[C:1]1([C:7]2[CH:12]=[CH:11][CH:10]=[C:9]([C:13]3[CH:18]=[CH:17][C:16](/[C:19](/[CH3:23])=[CH:20]/[CH2:21][OH:22])=[CH:15][CH:14]=3)[CH:8]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:24]([O:26][C@@H:27]([CH2:33][C:34]1[CH:39]=[CH:38][C:37](O)=[CH:36][CH:35]=1)[C:28]([O:30][CH2:31][CH3:32])=[O:29])[CH3:25]>>[CH2:24]([O:26][C@@H:27]([CH2:33][C:34]1[CH:35]=[CH:36][C:37]([O:22][CH2:21]/[CH:20]=[C:19](/[C:16]2[CH:15]=[CH:14][C:13]([C:9]3[CH:8]=[C:7]([C:1]4[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=4)[CH:12]=[CH:11][CH:10]=3)=[CH:18][CH:17]=2)\[CH3:23])=[CH:38][CH:39]=1)[C:28]([O:30][CH2:31][CH3:32])=[O:29])[CH3:25]