Ethyl 4-chlorosulfonyl-2-methylphenoxyacetate → Ethyl [4-(chlorosulfonyl)-2,5-dimethylphenoxy]acetate

HRID 985055Notes

Reaction equation

HRID 985055 reaction equation
[CH2:1]([O:3][C:4](=[O:18])[CH2:5][O:6][C:7]1[CH:12]=[CH:11][C:10]([S:13]([Cl:16])(=[O:15])=[O:14])=[CH:9][C:8]=1[CH3:17])[CH3:2].[CH2:19](OC(=O)COC1C=C(C)C=CC=1C)C>>[CH2:1]([O:3][C:4](=[O:18])[CH2:5][O:6][C:7]1[CH:12]=[C:11]([CH3:19])[C:10]([S:13]([Cl:16])(=[O:14])=[O:15])=[CH:9][C:8]=1[CH3:17])[CH3:2]

Participants

3

Reactant 2

HCID 11415129Ethyl 4-chlorosulfonyl-2-methylphenoxyacetateHCID 17065224Ethyl 2,5-dimethylphenoxyacetate

Product 1

HCID 20768123Ethyl [4-(chlorosulfonyl)-2,5-dimethylphenoxy]acetate

Procedure

The title compound was prepared according to the method described for preparing compound 10.2, using compound 21.1 as the starting material. 1H NMR (400 MHz) (CDCl3) δ 7.86 (1H, s); 6.61 (1H, s); 4.74 (2H, s); 4.30 (2H, q, J=7.1 Hz); 2.71 (3H, s); 2.31 (3H, s); 1.32 (3H, t, J=7.1 Hz).

Sources & evidence

ORD record
ord-c3ae1743be194e3f8f31eb94b50225cb
Source dataset
uspto-grants-2005_03
Patent number
US06869975B2

Reaction notes

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