Phosphorus pentachloride → HCID 86590608, compound

Participants

Reaction Conditions

Reaction Steps

Phosphorus pentachloride (4.1 g, 20 mmol) was slowly added dropwise with mono(2-ethylhexyl)maleate (4.5 g, 20 mmol) produced by Aldrich, while the temperature was maintained at 30° C. or lower. After completion of the addition, the reaction mixture was stirred at room temperature for 1 hour. Then, the reaction mixture was heated at 60° C., and pressure was reduced by using an aspirator. The produced oxyphosphorous chloride was evaporated to obtain 2-ethylhexyl maleate chloride (4.5 g, yield: 92%) as a brown oily compound.

Provenance & Evidence