HCID 841313, compound → Phenyl-(2-amino-5-nitrophenyl) sulfoxide

HRID 985909Notes

Reaction equation

HRID 985909 reaction equation
[C:1]1([S:7]([C:9]2[CH:14]=[CH:13][C:12](Cl)=[C:11]([N+:16]([O-:18])=[O:17])[CH:10]=2)=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C1(S(C2C=C([N+:33]([O-])=O)C=CC=2Cl)=O)C=CC=CC=1>>[C:1]1([S:7]([C:9]2[CH:10]=[C:11]([N+:16]([O-:18])=[O:17])[CH:12]=[CH:13][C:14]=2[NH2:33])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 2

HCID 841313HCID 841313, compoundHCID 200752752-(Benzenesulfinyl)-1-chloro-4-nitrobenzene

Product 1

HCID 22166205Phenyl-(2-amino-5-nitrophenyl) sulfoxide

Procedure

The procedure described in Example 20 is followed, except that as a starting material instead of phenyl-(4-chloro-3-nitrophenyl) sulfoxide a corresponding amount of phenyl-(2-chloro-5-nitrophenyl) sulfoxide is employed, and the reaction is carried out at 140° C. for 20 hours.

Sources & evidence

ORD record
ord-0b09a10b6c6b4f9590b4f069359873ac
Source dataset
uspto-grants-1987_12
Patent number
US04710323

Reaction notes

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