4-(4-Amino-3-nitrophenylsulfinyl)-biphenyl → HCID 20075276, compound

HRID 985913Notes

Reaction equation

HRID 985913 reaction equation
NC1C=CC(C2C=C(C)C=CC=2S(C2C=CC(C)=CC=2C2C=CC(N)=C([N+]([O-])=O)C=2)=O)=CC=1[N+]([O-])=O.[NH2:37][C:38]1[CH:43]=[CH:42][C:41]([S:44]([C:46]2[CH:51]=[CH:50][C:49]([C:52]3[CH:57]=[CH:56][CH:55]=[CH:54][CH:53]=3)=[CH:48][CH:47]=2)=[O:45])=[CH:40][C:39]=1[N+:58]([O-])=O>>[NH2:58][C:39]1[CH:40]=[C:41]([S:44]([C:46]2[CH:51]=[CH:50][C:49]([C:52]3[CH:57]=[CH:56][CH:55]=[CH:54][CH:53]=3)=[CH:48][CH:47]=2)=[O:45])[CH:42]=[CH:43][C:38]=1[NH2:37]

Participants

3

Reactant 2

HCID 200752594-(4-Amino-3-nitrophenylsulfinyl)-biphenylHCID 53642139(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxide

Product 1

HCID 20075276HCID 20075276, compoundYield 95%

Procedure

Following the procedure described in Example 40 but using as a starting material instead of (4-amino-3-nitrophenyl)-4-methylphenyl sulfoxide a corresponding amount of 4-(4-amino-3-nitrophenylsulfinyl)-biphenyl, the title compound is obtained.

Sources & evidence

ORD record
ord-5f85d2b708034f29aa45e059ae083b5d
Source dataset
uspto-grants-1987_12
Patent number
US04710323

Reaction notes

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