(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxide → HCID 53812587, compound

HRID 985918Notes

Reaction equation

HRID 985918 reaction equation
NC1C=CC(C2C=C(C)C=CC=2S(C2C=CC(C)=CC=2C2C=CC(N)=C([N+]([O-])=O)C=2)=O)=CC=1[N+]([O-])=O.[Br:37][C:38]1[CH:43]=[CH:42][C:41]([C:44]2[C:49]([N+:50]([O-])=O)=[C:48]([NH2:53])[CH:47]=[CH:46][C:45]=2[S:54]([C:56]2[CH:61]=[CH:60][C:59]([NH2:62])=[C:58]([N+:63]([O-])=O)[C:57]=2[C:66]2[CH:71]=[CH:70][C:69]([Br:72])=[CH:68][CH:67]=2)=[O:55])=[CH:40][CH:39]=1>>[Br:37][C:38]1[CH:39]=[CH:40][C:41]([C:44]2[C:49]([NH2:50])=[C:48]([NH2:53])[CH:47]=[CH:46][C:45]=2[S:54]([C:56]2[CH:61]=[CH:60][C:59]([NH2:62])=[C:58]([NH2:63])[C:57]=2[C:66]2[CH:71]=[CH:70][C:69]([Br:72])=[CH:68][CH:67]=2)=[O:55])=[CH:42][CH:43]=1

Participants

3

Reactant 2

HCID 53642139(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxideHCID 54156203HCID 54156203, compound

Product 1

HCID 53812587HCID 53812587, compound

Procedure

Following the procedure described in Example 40 but using as a starting material instead of (4-amino-3-nitrophenyl)-4-methylphenyl sulfoxide a corresponding amount of 4-bromophenyl-(4-amino-3-nitrophenyl) sulfoxide, the title compound is obtained.

Sources & evidence

ORD record
ord-f0a10559820e4ef281980b97f1a22a29
Source dataset
uspto-grants-1987_12
Patent number
US04710323

Reaction notes

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