HCID 20075264, compound → HCID 20075287, compound

HRID 985921Notes

Reaction equation

HRID 985921 reaction equation
NC1C=CC(C2C=C(C)C=CC=2S(C2C=CC(C)=CC=2C2C=CC(N)=C([N+]([O-])=O)C=2)=O)=CC=1[N+]([O-])=O.[Br:37][C:38]1[CH:43]=[CH:42][C:41]([C:44]2[CH:49]=[CH:48][C:47]([S:50]([C:52]3[CH:57]=[CH:56][C:55]([NH2:58])=[C:54]([N+:59]([O-])=O)[CH:53]=3)=[O:51])=[CH:46][CH:45]=2)=[CH:40][CH:39]=1>>[Br:37][C:38]1[CH:39]=[CH:40][C:41]([C:44]2[CH:45]=[CH:46][C:47]([S:50]([C:52]3[CH:57]=[CH:56][C:55]([NH2:58])=[C:54]([NH2:59])[CH:53]=3)=[O:51])=[CH:48][CH:49]=2)=[CH:42][CH:43]=1

Participants

3

Reactant 2

HCID 20075264HCID 20075264, compoundHCID 53642139(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxide

Product 1

HCID 20075287HCID 20075287, compound

Procedure

Following the procedure described in Example 40 but using as a starting material instead of (4-amino-3-nitrophenyl)-4-methylphenyl sulfoxide a corresponding amount of 1-(4-bromophenyl)-4-(4-amino-3-nitrophenylsulfinyl)-benzene, the title compound is obtained; M.P.=161°-164° C.

Sources & evidence

ORD record
ord-e17732bcb6f94d6586f17e75248d3f79
Source dataset
uspto-grants-1987_12
Patent number
US04710323

Reaction notes

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