(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxide → HCID 53905154, compound

HRID 985923Notes

Reaction equation

NC1C=CC(C2C=C(C)C=CC=2S(C2C=CC(C)=CC=2C2C=CC(N)=C([N+]([O-])=O)C=2)=O)=CC=1[N+]([O-])=O.[Cl:37][C:38]1[CH:43]=[CH:42][C:41]([C:44]2[CH:49]=[C:48]([CH3:50])[CH:47]=[CH:46][C:45]=2[S:51]([C:53]2[CH:58]=[CH:57][C:56]([CH3:59])=[CH:55][C:54]=2[C:60]2[CH:65]=[CH:64][C:63]([Cl:66])=[C:62]([N+:67]([O-])=O)[CH:61]=2)=[O:52])=[CH:40][C:39]=1[N+:70]([O-])=O>>[NH2:67][C:62]1[CH:61]=[C:60]([C:54]2[CH:55]=[C:56]([CH3:59])[CH:57]=[CH:58][C:53]=2[S:51]([C:45]2[CH:46]=[CH:47][C:48]([CH3:50])=[CH:49][C:44]=2[C:41]2[CH:42]=[CH:43][C:38]([Cl:37])=[C:39]([NH2:70])[CH:40]=2)=[O:52])[CH:65]=[CH:64][C:63]=1[Cl:66]

Participants

Reactant 2

HCID 53642139(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxide

HCID 53656366HCID 53656366, compound

Product 1

HCID 53905154HCID 53905154, compoundYield 88%

Procedure

Following the procedure described in Example 40 but using as a starting material instead of (4-amino-3-nitrophenyl)-4-methylphenyl sulfoxide a corresponding amount of (4-chloro-3-nitrophenyl)-4-methylphenyl sulfoxide, the title compound is obtained; M.P.=119°-121° C.

Sources & evidence

ORD record: ord-9f5d19e5c4e34718963bb64ccd1404c2
Source dataset: uspto-grants-1987_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04710323

Reaction notes

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