2-(Benzenesulfinyl)-1-chloro-4-nitrobenzene → HCID 20075256, compound

HRID 985924Notes

Reaction equation

HRID 985924 reaction equation
NC1C=CC(C2C=C(C)C=CC=2S(C2C=CC(C)=CC=2C2C=CC(N)=C([N+]([O-])=O)C=2)=O)=CC=1[N+]([O-])=O.[Cl:37][C:38]1[CH:43]=[CH:42][C:41]([N+:44]([O-])=O)=[CH:40][C:39]=1[S:47]([C:49]1[CH:54]=[CH:53][CH:52]=[CH:51][CH:50]=1)=[O:48]>>[NH2:44][C:41]1[CH:42]=[CH:43][C:38]([Cl:37])=[C:39]([S:47]([C:49]2[CH:54]=[CH:53][CH:52]=[CH:51][CH:50]=2)=[O:48])[CH:40]=1

Participants

3

Reactant 2

HCID 200752752-(Benzenesulfinyl)-1-chloro-4-nitrobenzeneHCID 53642139(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxide

Product 1

HCID 20075256HCID 20075256, compoundYield 89%

Procedure

Following the procedure described in Example 40 but using as a starting material instead of (4-amino-3-nitrophenyl)-4-methylphenyl sulfoxide a corresponding amount of (2-chloro-5-nitrophenyl)-phenyl sulfoxide, the title compound is obtained.

Sources & evidence

ORD record
ord-1764c1488c2f4a2fb4018443e628e5aa
Source dataset
uspto-grants-1987_12
Patent number
US04710323

Reaction notes

Loading…