(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxide → HCID 54377548, compound

HRID 985925Notes

Reaction equation

HRID 985925 reaction equation
NC1C=CC(C2C=C(C)C=CC=2S(C2C=CC(C)=CC=2C2C=CC(N)=C([N+]([O-])=O)C=2)=O)=CC=1[N+]([O-])=O.[Cl:37][C:38]1[CH:43]=[CH:42][C:41]([C:44]2[CH:49]=[C:48]([O:50][CH3:51])[CH:47]=[CH:46][C:45]=2[S:52]([C:54]2[CH:59]=[CH:58][C:57]([O:60][CH3:61])=[CH:56][C:55]=2[C:62]2[CH:67]=[CH:66][C:65]([Cl:68])=[C:64]([N+:69]([O-])=O)[CH:63]=2)=[O:53])=[CH:40][C:39]=1[N+:72]([O-])=O>>[NH2:69][C:64]1[CH:63]=[C:62]([C:55]2[CH:56]=[C:57]([O:60][CH3:61])[CH:58]=[CH:59][C:54]=2[S:52]([C:45]2[CH:46]=[CH:47][C:48]([O:50][CH3:51])=[CH:49][C:44]=2[C:41]2[CH:42]=[CH:43][C:38]([Cl:37])=[C:39]([NH2:72])[CH:40]=2)=[O:53])[CH:67]=[CH:66][C:65]=1[Cl:68]

Participants

3

Reactant 2

HCID 53642139(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxideHCID 53929863HCID 53929863, compound

Product 1

HCID 54377548HCID 54377548, compoundYield 86%

Procedure

Following the procedure described in Example 40 but using as a starting material instead of (4-amino-3-nitrophenyl)-4-methylphenyl sulfoxide a corresponding amount of (4-chloro-3-nitrophenyl)-4-methoxyphenyl sulfoxide, the title compound is obtained.

Sources & evidence

ORD record
ord-4b751ffb2be341209b1f29c988c52d61
Source dataset
uspto-grants-1987_12
Patent number
US04710323

Reaction notes

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