HCID 13536551, compound → HCID 13536550, compound

HRID 986348Notes

Reaction equation

HRID 986348 reaction equation
FC1C=CC=CC=1N1C(=S)C2C=CC=CC=2[Se]1.[CH2:18]1O[C:25]2[CH:24]=[CH:23][C:22]([N:27]3[C:31](=[S:32])[C:30]4[CH:33]=[CH:34][CH:35]=[CH:36][C:29]=4[Se:28]3)=[CH:21][C:20]=2[O:19]1.C1(CN2C(=S)C3C=CC=CC=3[Se]2)C=CC=CC=1.C1(CCCCN2C(=S)C3C=CC=CC=3[Se]2)C=CC=CC=1.C(N1C(=S)C2C=CC=CC=2[Se]1)C.CC1C=CC=CC=1N1C(=S)C2C=CC=CC=2[Se]1.C(N1C(=S)C2C=CC=CC=2[Se]1)CCC>>[CH3:18][O:19][C:20]1[CH:21]=[C:22]([N:27]2[C:31](=[S:32])[C:30]3[CH:33]=[CH:34][CH:35]=[CH:36][C:29]=3[Se:28]2)[CH:23]=[CH:24][CH:25]=1

Participants

8

Reactant 7

HCID 13536551HCID 13536551, compoundHCID 13536552HCID 13536552, compoundHCID 13536553HCID 13536553, compoundHCID 13536555HCID 13536555, compoundHCID 86741921HCID 86741921, compoundHCID 86741922HCID 86741922, compoundHCID 86741923HCID 86741923, compound

Product 1

HCID 13536550HCID 13536550, compound

Procedure

The following compounds were prepared analogously to the instructions of Example 2: 2-(2-fluorophenyl)-1,2-benzisoselenazole-3(2H)-thione, melting point 55°-57° C., 2-(3,4-methylenedioxyphenyl)-1,2-benzisoselenazol-3(2H)-thione, melting point 85°-88° C., 2-(phenylmethyl)-1,2-benzisoselenazole-3(2H)-thione, melting point 41° C., 2-(4-phenylbutyl)-1,2-benzisoselenazole-3(2H)-thione, oil, 2-ethyl-1,2-benzisoselenazole-3(2H)-thione, oil, 2-(2-methylphenyl)-1,2-benzisoselenazole-3(2H)-thione, melting point 65°-67° C. and 2-butyl-1,2-benzisoselenazole-3(2H)-thione, oil.

Workup

  1. customThe following compounds were prepared analogously to the instructions of Example 2

Sources & evidence

ORD record
ord-7f5eb9a5ae8e4a8e90eb5058ce54f4c4
Source dataset
uspto-grants-1987_12
Patent number
US04711961

Reaction notes

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