Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Sulfuric Acid | HCID 1118 | — |
| Reactant | Methacrolein | HCID 6562 | — |
| Reactant | Sodium 3-nitrobenzenesulfonate | HCID 31389 | — |
| Reactant | 2-Amino-4-chlorobenzoic acid | HCID 66646 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 13309791 | HCID 13309791 | — |
Reaction Steps
14 g of methacrolein were added dropwise, at 100° C., to a solution of 17 g of 4-chloroanthranilic acid and 19 g of sodium m-nitrobenzenesulfonate in 200 g of 57% strength sulfuric acid. The mixture was stirred for 1 hour at 130° C., after which it was diluted with 450 g of water and filtered under suction while hot. The pH was brought to 2-3 with concentrated sodium hydroxide solution, while cooling. The precipitated solid was filtered off under suction, washed with water and dried.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04715889 |
|---|
| Source dataset | uspto-grants-1987_12 |
|---|
| ORD ID | ord-c14bda0343034349b3c6e9cff6ffc507 |
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| Source note | uspto-grants-1987_12 |
|---|
