2-Isopropylphenol → HCID 18008637, compound

HRID 987365Notes

Reaction equation

[CH:1]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][C:5]=1[OH:10])([CH3:3])[CH3:2].[CH3:11][CH2:12][CH2:13][CH2:14][CH:15]([CH:17]([CH3:19])C)C.[CH3:20][CH2:21]CC(CC(C)C)C.CC(CC(C(C)C)C)C>>[CH:1]([C:4]1[CH:9]=[C:8]([CH2:20][CH2:21][CH2:19][CH2:17][CH2:15][CH2:14][CH2:13][CH2:12][CH3:11])[CH:7]=[CH:6][C:5]=1[OH:10])([CH3:3])[CH3:2]

Participants

Reactant 2

HCID 69432-Isopropylphenol

HCID 2637413987-01-4

Product 1

HCID 18008637HCID 18008637, compoundYield 266.4%

Procedure

2-Isopropylphenol (272.6 g, 2.0 mol), tripropylene (131.74 g), and Amberlyst 15 (8.55 g) were stirred for 7 h at 125° C. Work-up and in vacuo distillation as given for 1b gave 2-isopropyl-4-nonylphenol (239.4 g, 96.4% purity by GC area %) in 46% yield.

Workup

distillationWork-up and in vacuo distillation

Sources & evidence

ORD record: ord-e3d2fb20833e47a39fa8683667f7510c
Source dataset: uspto-grants-2003_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US06632410B2

Reaction notes

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