1,3-Propanediamine → HCID 15906157, compound

Participants

Reaction Steps

A mixture of 2,4-di-tert-butylphenol (50 mmol), propane-1,3-diamine (25 mmol) and 37% aqueous formaldehyde (50 mmol) was stirred in refluxing methanol for 2 h. The mixture was cooled to room temperature and the solid was filtered, and washed with methanol, yielding 14 in 10%. Spectroscopic data (not shown) supports formation of ligand precursor 14.

Provenance & Evidence