HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethylene → Methyl Acrylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethylene | HCID 6325 | — |
| Reactant | Methyl Acrylate | HCID 7294 | — |
| Reactant | Acrolein | HCID 7847 | — |
| Product | Methyl Acrylate | HCID 7294 | — |
| Product | Methyl formate | HCID 7865 | — |
Reaction Steps
Substantially the same procedure for producing MMA as described in Example 64 was repeated, except that the activated catalyst obtained in Example 62 was used, and that acrolein was used instead of the methacrolein. The reaction mixture obtained 10 hours after the start of the reaction was analyzed. As a result, it was found that the conversion of acrolein was 59.3%, the selectivity for methyl acrylate (MA) was 90.1%, and the selectivity for ethylene as a by-product was 1.83%, and that methyl formate was by-produced in an amount of 0.086 mol/mol of MA.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | USRE038283E1 |
| Source dataset | uspto-grants-2003_10 |
| ORD ID | ord-42389bc11b3043afafcb74d7924cf472 |
| Source note | uspto-grants-2003_10 |