huagongshe.com
HRID988946

反应详情

EQUATION

反应方程式

HRID 988946 的结构方程式

REACTANTS

反应物

3
结构：CC(C)(C)C(=O)C[S+]1CCCC1.[Br-]
HCID22564578

1-(3,3-Dimethyl-2-oxobutyl)thiolan-1-ium bromide

C10H19BrOS

2 次

结构：O=S(=O)([O-])C(F)(F)F.[K+]
HCID23664779

Potassium trifluoromethanesulfonate

CF3KO3S

结构：O=S(=O)([O-])C(F)(F)C(F)(F)C(F)(F)C(F)(F)F.[K+]
HCID23675274

Potassium perfluorobutanesulfonate

C4F9KO3S

PRODUCTS

生成物

1
结构：CC(C)(C)C(=O)C[S+]1CCCC1.O=S(=O)([O-])C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
HCID22564587

未命名化合物

收率 52%

PROCEDURE

实验过程

The synthesis was carried out under radiation from a yellow lamp. The synthesis was similar to the “Synthesis 5” except that the potassium trifluoromethanesulfonate and the 2-oxo-3,3-dimethylbutyl-thiacyclopentanium bromide were replaced with potassium nonafluorobutanesulfonate and 2-oxo-3,3,-dimethylbutyl-thiacyclopentanium bromide, respectively. The present inventors obtained 2-oxo-3,3-dimethylbutyl-thiacyclopentanium nonafluorobutanesulfonate. The yield was 52%, and the melting point was 79.5 degrees in centigrade.

WORKUP

后处理

  1. customThe synthesis was carried out under radiation from a yellow lamp