Glutathione → HCID 86583713, compound

HRID 989567Notes

Reaction equation

HRID 989567 reaction equation
[Cl-].[Cr+3:2].[Cl-].[Cl-].[NH2:5][C@@H:6]([CH2:10][CH2:11][C:12]([NH:14][C@H:15]([C:18]([NH:20][CH2:21][C:22]([OH:24])=[O:23])=[O:19])[CH2:16][SH:17])=[O:13])[C:7]([OH:9])=[O:8]>O>[Cr:2].[NH2:5][C@@H:6]([CH2:10][CH2:11][C:12]([NH:14][C@H:15]([C:18]([NH:20][CH2:21][C:22]([OH:24])=[O:23])=[O:19])[CH2:16][SH:17])=[O:13])[C:7]([OH:9])=[O:8]

Participants

4

Reactant 2

HCID 124886GlutathioneHCID 6452300Chromium(3+) trichloride

Product 1

HCID 86583713HCID 86583713, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Conditions

Temperature
40 °C

Procedure

One gram (3.7 mmole) of chromium chloride (CrCl3) was dissolved in 40 ml of deionized water to get a green solution. 4.6 g (15 mmole) of glutathione (GSH) was dissolved in 40 ml of deionized water were added, the pH of the reaction mixture adjusted to 6, and the reaction mixture was stirred for 3 hours at 40° C. until the solution turned violet. The absorbance peaks for Cr-GSH are 410 and 550 nm.

Workup

  1. customto get a green solution
  2. additionwere added

Sources & evidence

ORD record
ord-df729fb9ffa9459e9c507d3598e19146
Source dataset
uspto-grants-2002_10
Patent number
US06458351B2

Reaction notes

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