Hydroxide → HCID 22995147, compound

HRID 990580Notes

Reaction equation

HRID 990580 reaction equation
[I-].[CH2:2]([N+:6]1([CH:11]2[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12]2)[CH2:10][CH2:9][CH2:8][CH2:7]1)[CH2:3][CH2:4][CH3:5].[OH-:19]>O>[OH-:19].[CH2:2]([N+:6]1([CH:11]2[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12]2)[CH2:10][CH2:9][CH2:8][CH2:7]1)[CH2:3][CH2:4][CH3:5]

Participants

4

Reactant 2

HCID 961HydroxideHCID 22995133HCID 22995133, compound

Product 1

HCID 22995147HCID 22995147, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

N-butyl-N-cyclooctylpyrrolidinium iodide salt (95 gms., 0.26 mole) was dissolved in 300 ml. water in a 1000 ml. plastic bottle. To the solution, 300 gms. of Ion Exchange Resin OH (BIO RAD® AG1-X8) was added and the mixture was stirred at room temperature overnight. The mixture was filtered and the solids were rinsed with an additional 250 ml. of water. The original mixture was filtered and the rinse were combined and a small amount was titrated with 0.1N HCl to indicate the presence of 0.24 mol hydroxide (0.24 mol N-butyl-N-cyclooctylpyrrolidinium hydroxide) in the solution.

Workup

  1. additionof Ion Exchange Resin OH (BIO RAD® AG1-X8) was added
  2. filtrationThe mixture was filtered
  3. washthe solids were rinsed with an additional 250 ml
  4. filtrationThe original mixture was filtered

Sources & evidence

ORD record
ord-de7d292e00194631820f8064b8e6f655
Source dataset
uspto-grants-2002_10
Patent number
US06461580B1

Reaction notes

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