Distearylmethylamine → HCID 18417275, compound

HRID 991160Notes

Reaction equation

HRID 991160 reaction equation
[Cl:1][C:2]1[N:3]=[CH:4][NH:5][C:6]=1[Cl:7].[F:8][C:9]1[C:14]([B:15]([C:27]2[C:32]([F:33])=[C:31]([F:34])[C:30]([F:35])=[C:29]([F:36])[C:28]=2[F:37])[C:16]2[C:21]([F:22])=[C:20]([F:23])[C:19]([F:24])=[C:18]([F:25])[C:17]=2[F:26])=[C:13]([F:38])[C:12]([F:39])=[C:11]([F:40])[C:10]=1[F:41].[CH2:42]([N:60]([CH2:62][CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH2:68][CH2:69][CH2:70][CH2:71][CH2:72][CH2:73][CH2:74][CH2:75][CH2:76][CH2:77][CH2:78][CH3:79])[CH3:61])[CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH2:58][CH3:59]>C1(C)C=CC=CC=1>[F:33][C:32]1[C:27]([B:15]([C:14]2[C:9]([F:8])=[C:10]([F:41])[C:11]([F:40])=[C:12]([F:39])[C:13]=2[F:38])[C:16]2[C:17]([F:26])=[C:18]([F:25])[C:19]([F:24])=[C:20]([F:23])[C:21]=2[F:22])=[C:28]([F:37])[C:29]([F:36])=[C:30]([F:35])[C:31]=1[F:34].[F:33][C:32]1[C:27]([B:15]([C:14]2[C:9]([F:8])=[C:10]([F:41])[C:11]([F:40])=[C:12]([F:39])[C:13]=2[F:38])[C:16]2[C:17]([F:26])=[C:18]([F:25])[C:19]([F:24])=[C:20]([F:23])[C:21]=2[F:22])=[C:28]([F:37])[C:29]([F:36])=[C:30]([F:35])[C:31]=1[F:34].[CH2:62]([NH+:60]([CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH2:54][CH2:55][CH2:56][CH2:57][CH2:58][CH3:59])[CH3:61])[CH2:63][CH2:64][CH2:65][CH2:66][CH2:67][CH2:68][CH2:69][CH2:70][CH2:71][CH2:72][CH2:73][CH2:74][CH2:75][CH2:76][CH2:77][CH2:78][CH3:79].[Cl:1][C:2]1[N:3]=[CH:4][N-:5][C:6]=1[Cl:7]

Participants

5

Reactant 3

HCID 77709DistearylmethylamineHCID 1400184,5-DichloroimidazoleHCID 582056Tris(pentafluorophenyl)borane

Product 1

HCID 18417275HCID 18417275, compound

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

4,5-dichloroimidazole (0.2675 g, 1.953 mmol), tris(pentafluorophenyl)borane (2.0000 g, 3.9063 mmol) and dioctadecylmethylamine (1.0469 g, 1.9531 mmol) were placed in a 50 mL flask, taken up in 21 mL of toluene and refluxed under argon for hours. The volatiles were then stripped under vacuum. Yield, 2.937 g, 88.62 percent.

Workup

  1. temperaturerefluxed under argon for hours
  2. customYield

Sources & evidence

ORD record
ord-897fb63c4fd64c02ad02b40eafab3c23
Source dataset
uspto-grants-2002_10
Patent number
US06462156B2

Reaction notes

Loading…