2-Phenyl-7-chloroindene → 2-Phenyl-7-napthylindene

HRID 991990Notes

Reaction equation

HRID 991990 reaction equation
[C:1]1([C:7]2[CH2:8][C:9]3[C:14]([CH:15]=2)=[CH:13][CH:12]=[CH:11][C:10]=3Cl)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:17]1([Mg]Br)[C:26]2[C:21](=[CH:22][CH:23]=[CH:24][CH:25]=2)[CH:20]=[CH:19][CH:18]=1>>[C:1]1([C:7]2[CH2:8][C:9]3[C:14]([CH:15]=2)=[CH:13][CH:12]=[CH:11][C:10]=3[C:25]2[C:26]3[C:21](=[CH:20][CH:19]=[CH:18][CH:17]=3)[CH:22]=[CH:23][CH:24]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 2

HCID 184151592-Phenyl-7-chloroindeneHCID 178418298HCID 178418298, compound

Product 1

HCID 570158412-Phenyl-7-napthylindene

Procedure

2-phenyl-7-napthylindene is prepared in like manner from 2-phenyl-7-chloroindene (see Example I(a)) and naphthyl magnesium bromide.

Sources & evidence

ORD record
ord-82b2d7abc0f8449c8eb1f950d6108c29
Source dataset
uspto-grants-2002_10
Patent number
US06465700B1

Reaction notes

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