HuagongsheHuagongshe Chemistry Print Report · For research reference only
Oxygen → 1-Nitroadamantane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Oxygen | HCID 977 | — |
| Reactant | Adamantane | HCID 9238 | — |
| Reactant | N-Hydroxyphthalimide | HCID 10665 | — |
| Reactant | Nitrogen Dioxide | HCID 178526396 | — |
| Solvent | Acetic Acid | HCID 176 | — |
| Product | Adamantanone | HCID 64151 | 4% |
| Product | 1-Adamantanol | HCID 64152 | 1% |
| Product | 1-Nitroadamantane | HCID 64165 | 75% |
| Product | 1-Adamantyl acetate | HCID 519973 | 5% |
Reaction Steps
Into a flask, 1 mmole of adamantane, 0.1 mmole of N-hydroxyphthalimide, 15 mmole of nitrogen dioxide (NO2) and 3 ml of acetic acid were added and stirred for 5 hours at 60° C. in an atmosphere of oxygen. The reaction products were analyzed by gas chromatography, and, as a result, the conversion of adamantane was. 96%, and nitroadamantane (yield 75%), adamantanol (yield 1%), acetyloxyadamantane (yield 5%) and adamantanone (yield 4%) were formed.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06468487B1 |
| Source dataset | uspto-grants-2002_10 |
| ORD ID | ord-e8a5af2c19d64177a4931d80343ef331 |
| Source note | uspto-grants-2002_10 |