HuagongsheHuagongshe Chemistry Print Report · For research reference only
Peracetic Acid → Peracetic Acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Peracetic Acid | HCID 6585 | — |
| Reactant | Codeinone | HCID 5459910 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | Peracetic Acid | HCID 6585 | — |
| Product | (4R,4aS,12bS)-4a-hydroxy-9-methoxy-3-methyl-2,4,7a,13-tetrahydro-1H-4,12-methanobenzofuro[3,2-e]isoquinolin-7-one | HCID 5359420 | — |
Reaction Steps
14-Hydroxycodeinone was synthesized from the dienolsilyl ether of codeinone by oxidative hydroxylation using a peracetic acid solution preparation. The peracetic acid solution was prepared as follows:
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06469170B1 |
| Source dataset | uspto-grants-2002_10 |
| ORD ID | ord-95cd9d67a4dc4540b2c05bac8daca73d |
| Source note | uspto-grants-2002_10 |