Cyclopentanone → HCID 22889469, compound

HRID 992778Notes

Reaction equation

HRID 992778 reaction equation
[C:1]1(=[O:6])[CH2:5][CH2:4][CH2:3][CH2:2]1.Cl[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH:13]1[CH2:22][CH:21]2[CH2:23][CH:14]1[CH:15]1[CH:20]2[CH:19]2[CH2:24][CH:16]1[CH:17]=[CH:18]2>>[CH:15]12[CH:16]3[CH2:24][CH:19]([CH:18]=[CH:17]3)[CH:20]1[CH:21]1[CH2:23][CH:14]2[CH:13]([CH2:12][CH2:11][CH2:10][CH2:9][CH2:8][C:1]2([OH:6])[CH2:5][CH2:4][CH2:3][CH2:2]2)[CH2:22]1

Participants

3

Reactant 2

HCID 8452CyclopentanoneHCID 865854161-Chloro-5-(8-tetracyclo[4.4.0.12,5.17,10] dodecen-3-yl)pentane

Product 1

HCID 22889469HCID 22889469, compoundYield 82%

Procedure

1-{5-(8-Tetracyclo[4.4.0.12,5.17,10]dodecen-3-yl)pentyl}-cyclopentanol (yield: 82%) was obtained in the same manner as in Synthesis Example 1, except that cyclopentanone and 1-chloro-5-(8-tetracyclo[4.4.0.12,5.17,10] dodecen-3-yl)pentane were used in place of acetone and 1-chloro-4-(5-norbornen-2-yl)butane, respectively.

Sources & evidence

ORD record
ord-938b162dc9214bf9b3f81fc1b3a05e67
Source dataset
uspto-grants-2002_10
Patent number
US06469220B2

Reaction notes

Loading…