硫酸钾

Potassium Sulfate

HCID 24507CAS 7778-80-5

基本信息

标准SMILES
O=S(=O)([O-])[O-].[K+].[K+]
InChIKey
OTYBMLCTZGSZBG-UHFFFAOYSA-L
分子式
K2SO4
平均分子量
174.26 g/mol
单同位素质量
173.87914284

概述

Potassium sulfate is an inorganic potassium salt and a potassium salt.

名称与标识

首选名称
Potassium Sulfate
IUPAC
dipotassium;sulfate
中文名
硫酸钾
英文名
Potassium sulfate
分子式
K2O4S
分子量
174.2592

名称与别名

POTASSIUM SULFATE7778-80-5Dipotassium sulfatePotassium sulphateSulfuric acid dipotassium saltArcanum duplicatumSulfuric acid, dipotassium saltKalium sulphuricumTartarus vitriolatusKali sulphuricumPotassium sulfate (K2(SO4))K2SO4
展开更多名称
硫酸钾水硫酸硫酸钾粉农用硫酸钾無水硫酸鉀农业用钾肥高纯硫酸钾色谱硫酸钾色谱硫酸钾硫酸钾 溶液sop231-915-5KSOKso4KSO2KH2PO25WATER R PHEKaliumsulfat
Sulfuric acid potassium salt (1:2)1K573LC5TVPotassium (as sulfate)DTXSID6029701INS NO.515(I)INS-515(I)E-515(I)CHEBI:32036

数据库标识

CAS
7778-80-5、10233-01-9
PubChem CID
24507
DTXSID
DTXSID6029701
ChEMBL
CHEMBL2021424
ChEBI
CHEBI:32036
UNII
1K573LC5TV
EC Number
231-915-5
Nikkaji
J43.949E

性质

结构计算性质

极性表面积
88.6 Ų
氢键供体
0
氢键受体
4
可旋转键
0
重原子
7

实验与物化性质

Chemical ClassesMetals -> Metals, Inorganic Compounds
CosmeticsViscosity controlling; Bulking
pH · 2 条

Between 5,5 and 8,5 (5 % solution)

AQ SOLN IS NEUTRAL; PH ABOUT 7

SpringerMaterials Propertiesdielectric constant
OdorODORLESS
TasteHARD, BITTER, SALINE TASTE

物理化学性质

熔点
1067 °C · 1067°C
沸点
1689 °C · 1689°C
堆积密度
800 kg/m3 · 800kg/m3
密度
2.66 · 2.66
闪点
1689 °C · 1689°C
储存条件
Inert atmosphere,Room Temperature

化学性质

无色或白色六方形或斜方晶系结晶或颗粒状粉末。具有苦咸味。 溶于水,不溶于醇、丙酮和二硫化碳。

安全与法规

GHS分类

GHS Classification · 5 条

This chemical does not meet GHS hazard criteria for 89% (517 of 581) of all reports.

Danger

H318 (10.2%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

P264+P265, P280, P305+P354+P338, and P317 (click each P-code to see the statement)

Aggregated GHS information provided per 581 reports by companies from 9 notifications to the ECHA C&L Inventory.

危害信息

Regulatory Information · 5 条

Chemical: Sulfuric acid, dipotassium salt

Regulation (EC) No 1333/2008 (amended)

Sulfuric acid potassium salt (1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid potassium salt (1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 01-02-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/15527

Dipotassium sulphate: Non hazardous

Other Safety InformationIMAP assessments - Sulfuric acid, dipotassium salt: Human health tier I assessment
Fire HazardsNot combustible.
Hazards SummaryA mild skin, eye, and respiratory tract irritant; [ICSC] A mild skin irritant; [eChemPortal: ERMA] May cause irritation; [MSDSonline]
EPA Safer ChemicalChemical: Potassium sulfate
Chemical DangersDecomposes on heating. This produces sulfur oxides.

安全与防护

Fire FightingIn case of fire in the surroundings, use appropriate extinguishing media.
First Aid Measures · 4 条

Fresh air, rest.

Rinse and then wash skin with water and soap.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Give one or two glasses of water to drink.

Spillage DisposalSweep spilled substance into covered containers. Personal protection: particulate filter respirator adapted to the airborne concentration of the substance.
Eye PreventionWear safety goggles.
Inhalation RiskEvaporation at 20 °C is negligible; a nuisance-causing concentration of airborne particles can, however, be reached quickly when dispersed, especially if powdered.
Skin PreventionProtective gloves.

毒理信息

Signs and Symptoms · 4 条

Cough. Sore throat.

Redness.

Redness. Pain.

Abdominal pain. Diarrhoea. Nausea. Vomiting.

Human Toxicity ExcerptsSWALLOWING LARGE DOSES CAUSES SEVERE GI IRRITATION.
Non-Human Toxicity Excerpts · 1 条

CATTLE WHICH BROKE INTO FIELD WHICH HAD BEEN TREATED WITH POTASSIUM SULFATE DIED WITHIN 2 DAYS, SHOWING SYMPTOMS OF PROSTRATION, PARESIS, HYPOTHERMIA, CESSATION OF RUMINATION & CONSTIPATION. ONLY LESION SEEN @ POST MORTEM WAS CONGESTION OF MUCOUS MEMBRANE OF ABOMASUM & INTESTINES...

法规信息

State Drinking Water Standards · 2 条

(AL) ALABAMA 500,000 ug/l /Sulfate ion/

(UT) UTAH 1,000,000 ug/l /Sulfate ion/

State Drinking Water Guidelines · 2 条

(CA) CALIFORNIA 250 ug/l (Recommended); 500 ug/l (Upper); Short-term 600 ug/l /Sulfate ion/

(UT) UTAH 500,000 ug/l /Sulfate ion/

Federal Drinking Water GuidelinesEPA 250,000 ug/l /Sulfate ion/

安全数据

wgk
1
tsca
TSCA listed
毒性
LD50 orally in Rabbit: 6600 mg/kg
RTECS号
TT5900000
存储类别
13 - Non Combustible Solids
安全说明
22-24/25

毒性防护

毒性ADI不作特殊规定(FAO/WHO,2001。)GRAS(FDA,§184.1643,2000)。LD50 6600mg/kg(大鼠,经口)。

化学与工业

药理信息

Mechanism of Action · 1 条

Potassium is the major cation (positive ion) inside animal cells, while sodium is the major cation outside animal cells. The concentration differences of these charged particles causes a difference in electric potential between the inside and outside of cells, known as the membrane potential. The balance between potassium and sodium is maintained by ion pumps in the cell membrane. The cell membrane potential created by potassium and sodium ions allows the cell generate an action potential—a "spike" of electrical discharge. The ability of cells to produce electrical discharge is critical for body functions such as neurotransmission, muscle contraction, and heart function. Potassium is also an essential mineral needed to regulate water balance, blood pressure and levels of acidity.

FDA Pharmacological Classification · 6 条

KALI SULPHURICUM

Increased Large Intestinal Motility [PE]; Potassium Salt [EPC]; Potassium Compounds [CS]; Osmotic Laxative [EPC]; Inhibition Large Intestine Fluid/Electrolyte Absorption [PE]; Osmotic Activity [MoA]

POTASSIUM SULFATE

Inhibition Large Intestine Fluid/Electrolyte Absorption [PE]; Osmotic Activity [MoA]; Potassium Compounds [CS]; Osmotic Laxative [EPC]; Increased Large Intestinal Motility [PE]; Potassium Salt [EPC]

KALI SULPH

Inhibition Large Intestine Fluid/Electrolyte Absorption [PE]; Osmotic Activity [MoA]; Increased Large Intestinal Motility [PE]; Potassium Salt [EPC]; Potassium Compounds [CS]; Osmotic Laxative [EPC]

Absorption, Distribution and ExcretionMostly urine but also skin and feces.

用途与制造

Uses · 5 条

Used in gypsum cements, to make alum and glass, as a food additive, in fertilizers, as an accelerator in wallboard, as an expansion control agent for dental materials, as a medical and veterinary cathartic, and as a veterinary sulfate source; [HSDB]

Cement Producing [Category: Industry]

REAGENT IN ANALYTICAL CHEMISTRY; MEDICINE; GYPSUM CEMENTS; ALUM MFR; FOOD ADDITIVE

(VET): CATHARTIC, SULFATE SOURCE

FERTILIZER FOR CHLORIDE-SENSITIVE CROPS (EG, TOBACCO); ACCELERATOR IN WALLBOARD (CONSTRUCTION INDUSTRY); AGENT IN MFR OF GLASS; CATHARTIC IN HUMAN MEDICINE; WATER-CORRECTIVE AGENT FOR FOODS (EG, BREWERY WATER); SETTING-EXPANSION CONTROL AGENT FOR DENTAL MATERIALS

U.S. Exports · 3 条

(1978) 2.30X10+10 GRAMS

(1979) 2.24X10+10 GRAMS

(1985) 5.53x10+10 g

U.S. Imports · 3 条

(1977) 6.90X10+10 GRAMS

(1979) 2.02X10+10 GRAMS

(1985) 4.88X10+10 g

U.S. Production · 4 条

2023: 100,000,000 - <250,000,000 lb

(1977) 4.64X10+10 GRAMS (CONSUMPTION)

(1979) 4.11X10+10 GRAMS (CONSUMPTION)

(1985) 2.10X10+11 g

Consumption Patterns · 3 条

Agriculture, 63%; exports, 36%; other, 1% (1984)

CHEMICAL PROFILE: Potassium Sulfates. Fertilizer (mainly for non-grain or specialty crops), 56%; exports, 41%; other, 3%. /Potassium sulfates/

CHEMICAL PROFILE: Potassium sulfates. Demand: 1987: 227,600 tons K2O; 1988: 235,000 tons K2O; 1992 /projected/: 280,000 tons K2O. (Does not include imports, which totaled 30,000 tons K2O in 1987.) /Potassium sulfates/

Consumer UsesOther

应用领域

用途农业上硫酸钾可用作化学肥料,可使经济植物达到持续优质、高产,用于茶叶、蔬菜、水果等农作物。分析测试中硫酸钾血清蛋白生化检验,测定血钾及其他钾盐,凯氏定氮用催化剂。除此之外它还可在染料工业用于制中间体,玻璃工业用作澄清剂,香料工业用作助剂,医药上用作缓泻剂。它可食品工业用作通用添加剂,还用于血清蛋白生化检验。

制备方法 · 2 条

生产方法(1)曼海姆法。氯化钾和硫酸计量连续进入反应炉,反应生成固体硫酸钾,排出并冷却即为产品。尾气 (HCl29%) 经干燥、净化除尘、冷却,经进行吸收制得30%~33%的盐酸。反应式如下:(1)KCl+H2SO4→KHSO4+HCl↑ (2)KHSO4+KCl→K2SO4+HCl↑ (2)以氯化钾和芒硝(或硫酸钠)为原料的转化法。氯化钾和芒硝按一定比例配料,在水溶液中,常温条件下进行一段转化反应,反应产物经固液分离,得中间产品钾芒硝 (K2SO4·3Na2SO4),所得液相经蒸发析出NaCl(作为副产品),析盐母液经冷却析出部分钾芒硝后返回一段转化。一段转化反应式如下:6KCl+4Na2SO4·10H2O→3K2SO4·Na2SO4↓+6NaCl+40H2O 钾芒硝与氯化钾按一定比例配料,在水溶液中,常温条件下进行二段转化反应,固液分离得硫酸钾,母液返回第一段转化。二段转化反应如下:2KCl+3K2SO4·Na2SO4→4K2SO4↓+2NaCl (3)以氯化钾和硫酸镁为原料的转化法。氯化钾和硫酸镁按一定比例配料,在水溶液中,常温条件下进行一段转化反应,反应后经固液分离得软钾镁矾(K2SO4·MgSO4·6H2O),母液可用于生产氯化镁。一段转化反应式如下:2KCl+MgSO4·7H2O→K2SO4·MgSO4·6H2O↓+MgCl2+H2O 软钾镁矾与氯化钾按一定比例配料,在常温下经二段转化反应生成硫酸钾,再经固液分离、干燥、包装得成品硫酸钾。二段转化反应式如下:2KCl+K2SO4·MgSO4·6H2O→2K2SO4↓+MgCl2+6H2O

生产方法1. 曼海姆法:用98%硫酸和氯化钾在高温下进行分解反应,生成硫酸钾,副产盐酸。2. 结晶分离法:用桐子壳碱或草木灰碱经焙烧、浸取、过滤、浓缩、离心分离、干燥制得硫酸钾。3. 明矾石还原热解法:将明矾石粉碎、焙烧脱水,然后经脱色、用烧碱溶液浸取、脱硅、浓缩、分离得到粗硫酸钾,经精制制得硫酸钾成品。4. 制盐苦卤法:由氯化钾与硫酸或二氧化硫作用而得,或者由硫酸与氢氧化钾或碳酸钾中和而得。

试剂价格

030485 · 100g
硫酸钾, 99.99% (metals basis)Potassium sulfate, 99.99% (metals basis) — 6557元
P/7000 · 500g
硫酸钾Potassium sulfate, for analysi — 599元

供应商50 家

国药集团化学试剂有限公司86-21-63210123 · [email protected]
北京华美互利生物化工010-56205725 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
济南诚汇双达生物有限公司053158897070 15550412551
河北创海生物科技有限公司+86-86-13131129325 · [email protected]

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