Benzenamine, 4-ethoxy-N-phenyl- → 6-(Dimethylamino)-3-[4-(ethylbenzylamino)phenyl]-3-[(4-ethoxyphenyl)phenylamino]phthalide
反应方程式
[CH3:1][N:2]([CH3:30])[C:3]1[CH:4]=[CH:5][C:6]([C:12](=O)[C:13]2[CH:18]=[CH:17][C:16]([N:19]([CH2:27][CH3:28])[CH2:20][C:21]3[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=3)=[CH:15][CH:14]=2)=[C:7]([CH:11]=1)[C:8]([OH:10])=[O:9].[CH2:31]([O:33][C:34]1[CH:46]=[CH:45][C:37]([NH:38][C:39]2[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=2)=[CH:36][CH:35]=1)[CH3:32]>>[CH3:1][N:2]([CH3:30])[C:3]1[CH:11]=[C:7]2[C:6]([C:12]([C:13]3[CH:14]=[CH:15][C:16]([N:19]([CH2:27][CH3:28])[CH2:20][C:21]4[CH:22]=[CH:23][CH:24]=[CH:25][CH:26]=4)=[CH:17][CH:18]=3)([N:38]([C:37]3[CH:36]=[CH:35][C:34]([O:33][CH2:31][CH3:32])=[CH:46][CH:45]=3)[C:39]3[CH:44]=[CH:43][CH:42]=[CH:41][CH:40]=3)[O:9][C:8]2=[O:10])=[CH:5][CH:4]=1参与物
3
实验过程
Following a procedure similar to that described in Example 4 but employing 4.0 g of 5-(dimethylamino)-2-[4-(ethylbenzylamino)benzoyl]benzoic acid and 2.2 g of 4-ethoxy-N-phenyl aniline there was obtained 3.0 g of 6-(dimethylamino)-3-[4-(ethylbenzylamino)phenyl]-3-[(4-ethoxyphenyl)phenylamino]phthalide, m.p. 148°-152° C. A toluene solution of the product contacted with acidic clay or phenolic resin developed an orange-colored image which changed to green on clay after fluorescent light exposure.