海萝胶 → 肉桂酸

HRID 22091

反应方程式

HRID 22091 反应方程式
O[C:2]1[CH:12]=[CH:11][C:5]([CH:6]=[CH:7][C:8]([OH:10])=[O:9])=[CH:4][CH:3]=1.[OH-].[Na+].N#N.C1OC1CO.Cl>CS(C)=O.OCC(CO)O>[C:8]([OH:10])(=[O:9])[CH:7]=[CH:6][C:5]1[CH:4]=[CH:3][CH:2]=[CH:12][CH:11]=1

参与物

8

反应物 5

HCID 313海萝胶HCID 322对羟基肉桂酸HCID 947氮HCID 11164缩水甘油HCID 14798二甲基对苯二胺二盐酸

产物 1

HCID 8784肉桂酸

试剂、催化剂与溶剂 2

HCID 679二甲基亚砜溶剂HCID 753甘油溶剂

实验过程

8.719 g of p-hydroxy cinnamic acid was dissolved in 10 ml of DMSO, and 100 mg of sodium hydroxide was added. The mixture was stirred and heated to 90° C. under a flow of N2 gas. 19.7 g of glycidol was added gradually, heating and agitation was carried out for 2 hours, neutralized by adding hydrochloric acid and then the adduct of cinnamic acid and glycerin was obtained.

后处理

  1. temperatureheating

来源与证据

ORD记录
ord-b76ea8f01bb84b6080b39c1bfb6ab1c0
来源数据集
uspto-grants-1995_06
专利号
US05426210

关联笔记

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