氯化苄 → DIBENZYL SELENIDE

HRID 328049

反应方程式

HRID 328049 反应方程式
[Se].[BH4-].[Na+].[SeH2:4].[Na].[CH2:6](Cl)[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1>>[CH2:6]([Se:4][CH2:6][C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1

参与物

5

反应物 4

HCID 7503氯化苄HCID 4311764硼氢化钠HCID 6326970硒HCID 131710529CID 131710529

产物 1

HCID 98827DIBENZYL SELENIDE

实验过程

Into a 250 milliliter 3 necked round bottom flask equipped with an addition funnel and a magnetic stirring bar is placed 4.6 grams (0.058 moles) of selenium powder and 50 milliliters of deoxygenated distilled water. The flask is purged of air with nitrogen and a solution comprising 4.6 grams (0.122 moles) sodium borohydride in 50 milliliters of deoxygenated distilled water slowly added to the solution in the flask from the addition funnel. Upon contacting of these two solutions, vigorous hydrogen evolution occurs and the selenium powder is consumed thereby yielding a solution containing sodium hydrogen selenide. About 14.6 grams (0.166 moles) benzylchloride is now introduced into the flask and the resulting mixture stirred at room temperature for 18 hours. The solid product thus produced is collected by filtration washed with water and recrystallized twice from pentane. Yield 11.81 grams of rod like crystals, (m. p. 45° to 46° C).

后处理

  1. customof deoxygenated
  2. distillationdistilled water
  3. customThe flask is purged of air with nitrogen
  4. customof deoxygenated
  5. distillationdistilled water
  6. additionslowly added to the solution in the flask from the addition funnel
  7. customthe selenium powder is consumed
  8. customthereby yielding a solution
  9. customThe solid product thus produced
  10. filtrationis collected by filtration
  11. washwashed with water
  12. customrecrystallized twice from pentane

来源与证据

ORD记录
ord-7cf65154c6134671ba5f75e13ecb01a8
来源数据集
uspto-grants-1977_04
专利号
US04016058

关联笔记

加载中…