参与物
| 角色 | 名称 | HCID | 投料 |
|---|
| 反应物 | 甲苯 | HCID 1140 | — |
| 反应物 | 1-Iodo-3-triphenylmethoxy-trans-1-octene | HCID 20144636 | — |
| 反应物 | 正丁基锂 | HCID 178418339 | — |
| 溶剂 | 正己烷 | HCID 8058 | — |
| 产物 | HCID 178506898 | HCID 178506898 | — |
反应步骤
To a solution of 4.96 g. of 1-iodo-3-triphenylmethoxy-trans-1-octene (Example 730) in 10 ml. of toluene cooled to -78° C. is added under an inert atmosphere 1 molar equivalent of n-butyllithium dissolved in hexane. The reaction mixture is allowed to warm to -40° C. and is then maintained at that temperature for 1 hour to yield a hydrocarbon solution of 3-triphenylmethoxy-trans-1-octenyllithium.
来源与证据
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 专利号 | US04343949 |
|---|
| 来源数据集 | uspto-grants-1982_08 |
|---|
| ORD ID | ord-410e3cc6252d448fb060b596235a8194 |
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| 来源说明 | uspto-grants-1982_08 |
|---|
