2-Ethyl-6-methylaniline 分子结构式
HCID32485

2-Ethyl-6-methylaniline

C9H13N135.21 g/molCAS 24549-06-2

IDENTITY

结构与身份

标准SMILES
CCc1cccc(C)c1N
InChIKey
JJVKJJNCIILLRP-UHFFFAOYSA-N
分子式
C9H13N
平均分子量
135.21 g/mol
单同位素质量
135.10479942

COMPUTED

结构计算性质

已同步
XLogP
2.4
极性表面积
26 Ų
氢键供体
1
氢键受体
1
可旋转键
1
重原子
10
形式电荷
0
复杂度
101

PROPERTIES

实验与物化性质

Density

0.969 at 68 °F (USCG, 1999) - Less dense than water; will float

Flash Point

215 °F (USCG, 1999)

Boiling Point

447.8 °F at 760 mmHg (USCG, 1999)

Melting Point

-27.4 °F (USCG, 1999)

Physical Description

2-methyl-6-ethyl aniline appears as a clear liquid with a pungent odor. Water insoluble and less dense than water. Hence floats on water. (USCG, 1999)

Liquid

Kovats Retention Index

1217.7

GHS

GHS分类

GHS Classification

Danger

H302+H312+H332 (27.4%): Harmful if swallowed, in contact with skin or if inhaled [Warning Acute toxicity, oral; acute toxicity, dermal; acute toxicity, inhalation];H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral];H312 (59.4%): Harmful in contact with skin [Warning Acute toxicity, dermal];H331 (36.8%): Toxic if inhaled [Danger Acute toxicity, inhalation];H332 (55.7%): Harmful if inhaled [Warning Acute toxicity, inhalation];H412 (59.4%): Harmful to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P261, P264, P270, P271, P273, P280, P301+P317, P302+P352, P304+P340, P316, P317, P321, P330, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 106 reports by companies from 8 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

HAZARDS

危害信息

Regulatory Information

Chemical: Benzenamine, 2-ethyl-6-methyl-

Benzenamine, 2-ethyl-6-methyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzenamine, 2-ethyl-6-methyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 14-05-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/12644

Fire Hazards

Special Hazards of Combustion Products: Contain poisonous oxides of nitrogen and carbon dioxide.;Behavior in Fire: Produces poisonous gases. (USCG, 1999)

Health Hazards

Inhalation causes weakness, reduction in respiratory rate, coma, gradual respiratory failure, and mild cyanosis (high concentrations). Causes severe irritation of the eyes. Ingestion may produce cyanosis. (USCG, 1999)

Reactive Group

Amines, Aromatic

Reactivity Profile

2-METHYL-6-ETHYL ANILINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides.

Air and Water Reactions

Insoluble in water.

Hazard Classes and Categories

Acute Tox. 4 (100%);Acute Tox. 4 (59.4%);Acute Tox. 3 (36.8%);Acute Tox. 4 (55.7%);Aquatic Chronic 3 (59.4%)

SAFETY

安全与防护

Fire Fighting

Fire Extinguishing Agents: Water, dry chemical, foam, carbon dioxide. (USCG, 1999)

First Aid

INHALATION: Remove to fresh air; call a physician.;EYES: Flush eyes with plenty of running water for at least 15 minutes. Call a physician.;SKIN: Wash thoroughly with soap and water. Flush with running water for at least 15 minutes.;INGESTION: If victim is conscious, have victim drink water or milk and induce vomiting. (USCG, 1999)

Personal Protective Equipment (PPE)

Chemical goggles - face shield, protective gloves, organic vapor canister mask. (USCG, 1999)

TOXICITY

毒理信息

USGS Health-Based Screening Levels for Evaluating Water-Quality

2-Ethyl-6-methylaniline

Pesticide degradation product

Smith, C.D. and Nowell, L.H., 2024. Health-Based Screening Levels for evaluating water-quality data (3rd ed.). DOI:10.5066/F71C1TWP

REGULATORY

法规信息

Regulatory Information

Chemical: Benzenamine, 2-ethyl-6-methyl-

Benzenamine, 2-ethyl-6-methyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzenamine, 2-ethyl-6-methyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 14-05-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/12644

USES

用途与制造

U.S. Production

2023: 40,000,000 - <55,000,000 lb;2022: 40,000,000 - <55,000,000 lb;2021: 25,000,000 - <40,000,000 lb;2020: 40,000,000 - <55,000,000 lb

Industry Uses

Intermediate;Processing aids not otherwise specified

General Manufacturing Information

Pesticide, Fertilizer, and Other Agricultural Chemical Manufacturing

Benzenamine, 2-ethyl-6-methyl-: ACTIVE

ALIASES

名称与别名

共 66 条
2-ETHYL-6-METHYLANILINE24549-06-26-Ethyl-o-toluidineBenzenamine, 2-ethyl-6-methyl-2-Methyl-6-ethylanilineo-Toluidine, 6-ethyl-6-Ethyl-2-methylanilineDTXSID7027833C 25702DTXCID40783332Y3271G51RefChem:471877246-309-62-ethyl-6-methyl-aniline2-Ethyl-6-methylbenzenamineMFCD00007752Aniline, 2-methyl-6-ethyl-6-ethyl-2-methylphenylamine6-Ethyl-2-toluidine2-Methyl-6-ethyl aniline

REACTIONS

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