Trimethyl[(1-phenylvinyl)oxy]silan

Benzene, [1-[(trimethylsilyl)oxy]ethenyl]-

HCID 117406CAS 13735-81-4

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Grundinformationen

Standard-SMILES: C=C(O[Si](C)(C)C)c1ccccc1
InChIKey: AFFPCIMDERUIST-UHFFFAOYSA-N
Summenformel: C11H16OSi
Durchschnittliche Molmasse: 192,33 g/mol
Monoisotopische Masse: 192,09704166

Namen und Bezeichner

Bevorzugter Name: Benzene, [1-[(trimethylsilyl)oxy]ethenyl]-
IUPAC: trimethyl(1-phenylethenoxy)silane
Lokaler Name: Trimethyl[(1-phenylvinyl)oxy]silan
Englischer Name: 1-Phenyl-1-trimethylsiloxyethylene
Summenformel: C11H16OSi
Molmasse: 192.33

Namen und Synonyme

Trimethyl((1-phenylvinyl)oxy)silaneTrimethyl[(1-phenylvinyl)oxy]silaneEINECS 237-308-11-Phenyl-1-(trimethylsiloxy)ethylenealpha-(Trimethylsiloxy)styreneBenzene, (1-((trimethylsilyl)oxy)ethenyl)-Silane, trimethyl((1-phenylethenyl)oxy)-Silane, trimethyl[(1-phenylethenyl)oxy]-DTXSID10884636Benzene, [1-[(trimethylsilyl)oxy]ethenyl]-RefChem:562065DTXCID101024066

Weitere Namen anzeigen

DK071DKFELEX0126α-(trimethylsiloxy)styreneà-(trimethylsiloxy)styreneα-(Trimethylsilyloxy)styrene1-Phenyl-1-trimethylsiloxyetheneALPHA-(TRIMETHYLSILYLOXY)STYRENE(1-phenylvinyl)oxyTrimethylsilane

237-308-113735-81-41-Phenyl-1-trimethylsiloxyethylenetrimethyl(1-phenylethenoxy)silane1-Phenyl-1-trimethylsilyloxyethyleneC11H16OSiMFCD000085821-Phenyl-1-(trimethylsilyloxy)ethylene

Datenbank-Bezeichner

CAS: 13735-81-4
PubChem CID: 117406
DTXSID: DTXSID10884636
UNII: X26FF7XFN5
EC Number: 237-308-1
Nikkaji: J236.395J

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 9,2 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 1
Frei drehbare Bindungen: 3
Schwere Atome: 13
Formalladung: 0
Komplexität: 175

Physikochemische Eigenschaften

Schmelzpunkt: 122 · 122-123 °C
Siedepunkt: 88 · 88-89 °C/11 mmHg (lit.)
Dichte: 0.938 g/mL · 0.938 g/mL at 25 °C (lit.)
Dampfdichte: 1 · >1 (vs air)
Brechungsindex: 20 · n20/D 1.502(lit.)
Flammpunkt: 174 °F · 174 °F
storage temp.: 2 · 2-8°C
Aggregatzustand: clear liquid
Farbe: Colorless to Light orange to Yellow
Wichte: 0.938 · 0.938
Wasserlöslichkeit: Reacts with water.
BRN: 1306914 · 1306914
InChI: 1S/C11H16OSi/c1-10(12-13(2,3)4)11-8-6-5-7-9-11/h5-9H,1H2,2-4H3
InChIKey: AFFPCIMDERUIST-UHFFFAOYSA-N
SMILES: C[Si](C)(C)OC(=C)c1ccccc1
CAS Datenbank: 13735 · 13735-81-4(CAS DataBase Reference)
EPA chemische Informationen: Silane, trimethyl[(1-phenylethenyl)oxy]- (13735-81-4)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (97.5%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Hazard Classes and CategoriesSkin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (97.5%)

Sicherheitsdaten

F: 10-21
wgk: 3
tsca: TSCA listed
hs_code: 2931900090
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36
Speicherklasse: 10 - Combustible liquids
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing InformationBenzene, [1-[(trimethylsilyl)oxy]ethenyl]-: ACTIVE

Anwendungen · 1 Eintrag

Verwenden1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of β-amino ketones in water via Mannich-type reaction and cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction. It is also used as chemical additives and intermediates.