Triphenylbismut
Triphenylbismuth
Grundinformationen
- CAS
603-33-8- Standard-SMILES
c1cc[c]([Bi]([c]2ccccc2)[c]2ccccc2)cc1- InChIKey
ZHXAZZQXWJJBHA-UHFFFAOYSA-N- Summenformel
- C18H15Bi
- Durchschnittliche Molmasse
- 440,3 g/mol
- Monoisotopische Masse
- 440,09777
Überblick
structure given in first source
Namen und Bezeichner
- Bevorzugter Name
- Triphenylbismuth
- IUPAC
- triphenylbismuthane
- Lokaler Name
- Triphenylbismut
- Englischer Name
- Triphenylbismuth
- Summenformel
- C18H15Bi
- Molmasse
- 440.29
Namen und Synonyme
Triphenylbismuth603-33-8TriphenylbismuthineTriphenyl bismuthBISMUTHINE, TRIPHENYL-AerotexTrifenylbismutinDTXSID6042498Triphenyl bismuthinePh3BiNSC-465R18732F41W
Weitere Namen anzeigen
TPB(C6H5)3Bitriphenyl-bismuthinTriphenylbismuth,99%Triphenylbismuth,98%
DTXCID4022498RefChem:191900210-033-4triphenylbismuthaneBismuth triphenylBismuth, triphenyl-Caswell No. 896triphenylbismuthin
Datenbank-Bezeichner
- CAS
603-33-8- PubChem CID
- 11774
- DTXSID
DTXSID6042498- UNII
- R18732F41W
- EC Number
- 210-033-4
- Nikkaji
- J42.067K
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 0 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 0
- Frei drehbare Bindungen
- 3
- Schwere Atome
- 19
- Formalladung
- 0
- Komplexität
- 202
Experimentelle und physikochemische Eigenschaften
Chemical ClassesMetals -> Metals, Organic Compounds
Vapor Pressure0.000034 [mmHg]
Physical Description
CBI
Solid; [Merck Index] White to off-white powder; [Alfa Aesar MSDS]
Physikochemische Eigenschaften
- Schmelzpunkt
- 78 · 78-80 °C
- Siedepunkt
- 310 °C · 310°C
- Dichte
- 1 · 1,585 g/cm3
- Brechungsindex
- 1.704 · 1.7040
- Flammpunkt
- 242 °C/14mm · 242°C/14mm
- storage temp.
- Inert atmosphere,Room Temperature
- Löslichkeit
- Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
- Aggregatzustand
- crystal
- Farbe
- white
- Wichte
- 1.585 · 1.585
Sicherheit und Regulatorisches
Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.
GHS-Klassifizierung
GHS Classification
This chemical does not meet GHS hazard criteria for 2.1% (1 of 47) of reports.
Warning
H302 (95.7%): Harmful if swallowed [Warning Acute toxicity, oral]
P261, P264, P270, P271, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 47 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Regulatory Information
Hazard Traits - Bioaccumulation; Environmental Persistence
Bismuthine, triphenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Bismuthine, triphenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Bismuthine, triphenyl-: Does not have an individual approval but may be used under an appropriate group standard
Hazards SummaryMay cause irritation; Harmful by ingestion; [Alfa Aesar MSDS] See Triphenylantimony.
Hazard Classes and CategoriesAcute Tox. 4 (95.7%)
Sicherheitsdaten
- wgk
- 3
- tsca
- TSCA listed
- hs_code
- 2931900090
- RTECS-Nr.
- EB2980000
- risk_code
- 20/21/22
- hazard_code
- Xn
Chemie und Industrie
Verwendung und Herstellung
UsesUsed as a radiopacifying agent in dental resins and medical devices, polymerization catalyst, and in organic synthesis; [Merck Index]
U.S. Production2023: <50,000 lb
Industry UsesOther
General Manufacturing Information
All Other Chemical Product and Preparation Manufacturing
Bismuthine, triphenyl-: ACTIVE
Anwendungen
VerwendenTriphenylbismuth, as an volatile organometallic used in the preparation of thin films of superconducting oxides by CVD. It is also added to the fuel of rocket as cruing agent. It acts as a solidifying catalyst for butyl hydroxyl propellants.
Darstellung
synthetischeTriphenylbismuth is conveniently prepared by reaction of Phenylmagnesium Bromide with BiCl3 in ether.
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Vorgelagerte Rohstoffe
Nachgelagerte Produkte
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