Triphenylbismut

Triphenylbismuth

HCID 11774CAS 603-33-8

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Grundinformationen

Standard-SMILES: c1cc[c]([Bi]([c]2ccccc2)[c]2ccccc2)cc1
InChIKey: ZHXAZZQXWJJBHA-UHFFFAOYSA-N
Summenformel: C18H15Bi
Durchschnittliche Molmasse: 440,3 g/mol
Monoisotopische Masse: 440,09777418

Überblick

structure given in first source

Namen und Bezeichner

Bevorzugter Name: Triphenylbismuth
IUPAC: triphenylbismuthane
Lokaler Name: Triphenylbismut
Englischer Name: Triphenylbismuth
Summenformel: C18H15Bi
Molmasse: 440.29

Namen und Synonyme

Triphenylbismuth603-33-8TriphenylbismuthineTriphenyl bismuthBISMUTHINE, TRIPHENYL-AerotexTrifenylbismutinDTXSID6042498Triphenyl bismuthineNSC-465R18732F41WDTXCID4022498

Weitere Namen anzeigen

TPB(C6H5)3Bitriphenyl-bismuthinTriphenylbismuth,99%Triphenylbismuth,98%

Ph3BiRefChem:191900210-033-4triphenylbismuthaneBismuth triphenylBismuth, triphenyl-MFCD00014064Caswell No. 896

Datenbank-Bezeichner

CAS: 603-33-8
PubChem CID: 11774
DTXSID: DTXSID6042498
UNII: R18732F41W
EC Number: 210-033-4
Nikkaji: J42.067K

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 0 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 0
Frei drehbare Bindungen: 3
Schwere Atome: 19
Formalladung: 0
Komplexität: 202

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Metals, Organic Compounds

Vapor Pressure0.000034 [mmHg]

Physical Description · 2 Einträge

CBI

Solid; [Merck Index] White to off-white powder; [Alfa Aesar MSDS]

Physikochemische Eigenschaften

Schmelzpunkt: 78 · 78-80 °C
Siedepunkt: 310 °C · 310°C
Dichte: 1 · 1,585 g/cm3
Brechungsindex: 1.704 · 1.7040
Flammpunkt: 242 °C/14mm · 242°C/14mm
storage temp.: Inert atmosphere,Room Temperature
Löslichkeit: Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly)
Aggregatzustand: crystal
Farbe: white
Wichte: 1.585 · 1.585
Wasserlöslichkeit: insoluble
CAS Datenbank: 603 · 603-33-8(CAS DataBase Reference)
NIST chemische Informationen: Bismuthine, triphenyl-(603-33-8)
EPA chemische Informationen: Triphenylbismuth (603-33-8)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

This chemical does not meet GHS hazard criteria for 2.1% (1 of 47) of reports.

Warning

H302 (95.7%): Harmful if swallowed [Warning Acute toxicity, oral]

P261, P264, P270, P271, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 3 Einträge

Hazard Traits - Bioaccumulation; Environmental Persistence

Bismuthine, triphenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Bismuthine, triphenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Bismuthine, triphenyl-: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryMay cause irritation; Harmful by ingestion; [Alfa Aesar MSDS] See Triphenylantimony.

Hazard Classes and CategoriesAcute Tox. 4 (95.7%)

Sicherheitsdaten

wgk: 3
tsca: TSCA listed
hs_code: 29319090
RTECS-Nr.: EB2980000
risk_code: 20/21/22
hazard_code: Xn
safety_code: 24/25-36/37

Chemie und Industrie

Verwendung und Herstellung

UsesUsed as a radiopacifying agent in dental resins and medical devices, polymerization catalyst, and in organic synthesis; [Merck Index]

U.S. Production2023: <50,000 lb

Industry UsesOther

General Manufacturing Information · 2 Einträge

All Other Chemical Product and Preparation Manufacturing

Bismuthine, triphenyl-: ACTIVE

Anwendungen · 1 Eintrag

VerwendenTriphenylbismuth, as an volatile organometallic used in the preparation of thin films of superconducting oxides by CVD. It is also added to the fuel of rocket as cruing agent. It acts as a solidifying catalyst for butyl hydroxyl propellants.