Methacrylic Acid → Triphenyl bismuth (V) methacrylate

HRID 1493115

Reaktionsgleichung

Reaktionsgleichung von HRID 1493115
[C:1]1([Bi:7]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[C:20]([OH:25])(=[O:24])[C:21]([CH3:23])=[CH2:22].C(OO)(C)(C)C>C(OCC)C>[C:20]([O-:25])(=[O:24])[C:21]([CH3:23])=[CH2:22].[C:14]1([Bi+2:7]([C:1]2[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:15]=[CH:16][CH:17]=[CH:18][CH:19]=1.[C:20]([O-:25])(=[O:24])[C:21]([CH3:23])=[CH2:22]

Komponenten

5

Edukt 3

HCID 4093Methacrylic AcidHCID 6410tert-Butyl hydroperoxideHCID 11774Triphenylbismuth

Produkt 1

HCID 19830615Triphenyl bismuth (V) methacrylate

Reagenzien, Katalysatoren, Lösungsmittel 1

HCID 3283Diethyl EtherLösungsmittel

Versuchsvorschrift

The general method as outlined by V. A. Dodonov, A. V. Gustichin and T. G. Brilkina (Zh. Obsch. Khim 55, 1(73) 1985) was followed for the preparation of this compound. The details of a typical preparation are: Triphenyl bismuthine (4.4 g, 0.01 mol.), methacrylic acid (1.97 g) (0.02 mol), tert-butyl hydroperoxide (1.39 g) were mixed with 20 ml of diethyl ether in a round bottom flask. The contents were stirred overnight (20 hr) at ambient temperature. The volatile matter was then removed in vacuo (0.1 mm Hg) for 5 hr to obtain a solid which was analyzed for its metal content.

Aufarbeitung

  1. customBrilkina (Zh. Obsch. Khim 55, 1(73) 1985) was followed for the preparation of this compound
  2. customThe details of a typical preparation
  3. customThe volatile matter was then removed in vacuo (0.1 mm Hg) for 5 hr
  4. customto obtain a solid which

Quellen und Nachweise

ORD-Eintrag
ord-32d84826fcbb49c1928fcb3e2ecb49a8
Quelldatensatz
uspto-grants-1991_06
Patentnummer
US05021398

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