3-Nitro-o-toluidin

2-Methyl-3-nitroaniline

HCID 11783CAS 603-83-8

Grundinformationen

Standard-SMILES
Cc1c(N)cccc1[N+](=O)[O-]
InChIKey
HFCFJYRLBAANKN-UHFFFAOYSA-N
Summenformel
C7H8N2O2
Durchschnittliche Molmasse
152,15 g/mol
Monoisotopische Masse
152,0585775

Überblick

2-methyl-3-nitroaniline appears as yellow rhombic needles (from water) or bright yellow powder. (NTP, 1992)

Namen und Bezeichner

Bevorzugter Name
2-Methyl-3-nitroaniline
IUPAC
2-methyl-3-nitroaniline
Lokaler Name
3-Nitro-o-toluidin
Englischer Name
2-Methyl-3-nitroaniline
Summenformel
C7H8N2O2
Molmasse
152.15

Namen und Synonyme

2-Methyl-3-nitroaniline603-83-82-Amino-6-nitrotoluene3-NITRO-O-TOLUIDINEBenzenamine, 2-methyl-3-nitro-o-Toluidine, 3-nitro-2-methyl-3-nitrobenzenamine1-Amino-2-methyl-3-nitrobenzeneDTXSID8025628D3JC433CEB6-nitro-2-aminotoluene6-Amino-2-nitrotoluene
Weitere Namen anzeigen
-3-nitroaniL3-nitro-o-toluidinMethyl-3-nitroanilLABOTEST-BB LTBB0006222-Methy-3-nitroaniline2-NITRO-6-AMINOTOLUENE
NSC-227939DTXCID505628NSC-25011RefChem:475379210-059-62-methyl-3-nitro-anilineMFCD000077312-methyl-3-nitro-phenylamine

Datenbank-Bezeichner

CAS
603-83-8
PubChem CID
11783
DTXSID
DTXSID8025628
ChEMBL
CHEMBL1882292
UNII
D3JC433CEB
EC Number
210-059-6
Nikkaji
J85.099C

Eigenschaften

Berechnete Struktureigenschaften

XLogP
1,8
Polarare Oberfläche (TPSA)
71,8 Ų
H-Brücken-Donoren
1
H-Brücken-Akzeptoren
3
Frei drehbare Bindungen
0
Schwere Atome
11

Experimentelle und physikochemische Eigenschaften

Solubilityless than 1 mg/mL at 73 °F (NTP, 1992)
Boiling Point581 °F at 760 mmHg (decomposes) (NTP, 1992)
Melting Point198 °F (NTP, 1992)
Physical Description2-methyl-3-nitroaniline appears as yellow rhombic needles (from water) or bright yellow powder. (NTP, 1992)

Physikochemische Eigenschaften

Schmelzpunkt
88 · 88-90 °C (lit.)
Siedepunkt
305 °C · 305 °C (lit.)
Dichte
1.378 · 1.378
Brechungsindex
1.6394 · 1.6394 (estimate)
Flammpunkt
305 °C · 305°C
storage temp.
30 °C · Store below +30°C.

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P260, P261, P262, P264, P270, P271, P273, P280, P301+P316, P302+P352, P304+P340, P316, P319, P321, P330, P361+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 48 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 2 Einträge

Chemical: Benzenamine, 2-methyl-3-nitro-

2-Methyl-3-nitroaniline: Does not have an individual approval but may be used under an appropriate group standard

DOT LabelPoison
Fire HazardsFlash point data for this chemical are not available; however, it is probably combustible. (NTP, 1992)
Health HazardsSYMPTOMS: Symptoms of exposure to this compound include skin and eye irritation.
Reactive GroupNitro, Nitroso, Nitrate, and Nitrite Compounds, Organic
Reactivity Profile2-METHYL-3-NITROANILINE is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizers. (NTP, 1992)

Sicherheit und Schutzausrüstung

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. A water spray may also be used. (NTP, 1992)
First Aid · 1 Eintrag

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 Eintrag

SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with 60-70% ethanol and transfer the dampened material to a suitable container. Use absorbent paper dampened with 60-70% ethanol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:
Personal Protective Equipment (PPE) · 1 Eintrag

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Sicherheitsdaten

wgk
3
ridadr
UN 2660 6.1/PG 3
hs_code
29214300
RTECS-Nr.
XU8200000
risk_code
23/24/25-33-51/53
hazard_code
T,N

Chemie und Industrie

Anwendungen

Verwenden2-Amino-6-nitrotoluene (2-Methyl-3-nitroaniline) has been used as a standard while evaluating the potential for degradation of nitroaromatic compounds by indigenous microorganisms.

Anbieter50 Anbieter

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