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Hydroxylammoniumsulfat

Hydroxylamine, sulfate (1:1)

HCID 159255
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Grundinformationen

CAS
10039-54-0
Standard-SMILES
NO.O=S(=O)(O)O
InChIKey
NXPHCVPFHOVZBC-UHFFFAOYSA-N
Summenformel
H3NO.H2O4S
Durchschnittliche Molmasse
131,11 g/mol
Monoisotopische Masse
130,98884326

Namen und Bezeichner

Bevorzugter Name
Hydroxylamine, sulfate (1:1)
IUPAC
hydroxylamine;sulfuric acid
Lokaler Name
Hydroxylammoniumsulfat
Englischer Name
Hydroxylamine sulfate
Summenformel
H2O4S.2H3NO
Molmasse
164.14

Namen und Synonyme

10046-00-1Hydroxylammonium hydrogensulphateHydroxylamine, sulfate (1:1)Hydroxylammonium acid sulfateDTXSID9064928EINECS 233-154-4Hydroxylamine, sulfate (1:1) (salt)RefChem:789514DTXCID4032534hydroxylamine;sulfuric acidHydroxylamine sulfate (1:1)H5NO5S
Weitere Namen anzeigen
HYDROXYLAMINE SULPHATEHASHYDROXYLAMMONIUM SULFATEHYDROXYLAMMONIUM SULPHATEHydroxylammoniumHydroxylammoniumsulfatHuHAS1amine suLHA synthase 1
Hydroxyamine sulfatehydroxylamin hydrogensulfateNH2OH H2SO4SCHEMBL18616SCHEMBL3888555SCHEMBL9196893SCHEMBL9413460Sulfuric acid--hydroxylamine (1/1)

Datenbank-Bezeichner

CAS
10039-54-0、10046-00-1
PubChem CID
159255
DTXSID
DTXSID9064928
EC Number
233-154-4

Eigenschaften

Berechnete StruktureigenschaftenWird ergänzt

Polarare Oberfläche (TPSA)
129 Ų
H-Brücken-Donoren
4
H-Brücken-Akzeptoren
6
Frei drehbare Bindungen
0
Schwere Atome
7
Formalladung
0
Komplexität
83,3

Experimentelle und physikochemische Eigenschaften

DensityRelative density (water = 1): 1.9
SolubilitySolubility in water: good
Decomposition57 °C
Physical DescriptionWHITE-TO-BROWN HYGROSCOPIC CRYSTALS.

Physikochemische Eigenschaften

Schmelzpunkt
170 °C · 170 °C (dec.)(lit.)
Siedepunkt
56.5 ℃ · 56.5℃
Dichte
1.86 · 1.86
Dampfdruck
0.001 Pa · 0.001Pa at 20℃
storage temp.
-20 °C · -20°C
Löslichkeit
water: soluble(lit.)
Aggregatzustand
Crystals
Farbe
White
PH
3.6 · 3.6 (10g/l, H2O, 20℃)
Biologische Quelle
mouse

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

Gefahrenhinweise

Regulatory Information · 2 Einträge

Chemical: Hydroxylamine, sulfate (1:1) (salt)

Hydroxylamine, sulfate (1:1) (salt): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Other Safety InformationIMAP assessments - Hydroxylamine and its salts: Human health tier II assessment
Fire HazardsNot combustible. Gives off irritating or toxic fumes (or gases) in a fire.
EC ClassificationSymbol: Xn, N; R: 22-36/38-43-48/22-50; S: (2)-22-24-37-61
UN ClassificationUN Hazard Class: 9; UN Pack Group: III
Chemical DangersDecomposes on heating. This produces corrosive fumes. The substance is a weak acid. Attacks many metals. This produces flammable/explosive gas (hydrogen - see ICSC 0001).

Sicherheit und Schutzausrüstung

Fire FightingUse water in large amounts, powder, alcohol-resistant foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.
First Aid Measures · 4 Einträge

Fresh air, rest. Refer for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Give a slurry of activated charcoal in water to drink. Refer for medical attention .

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing InformationHydroxylamine, sulfate (1:1): ACTIVE

Anwendungen

VerwendenHydroxylamine sulfate may be used to prepare highly sensitive cellulose tape, used for the detection of formaldehyde gas. It may be used in the quantitative determination of perchlorate in biological fluids by spectrophotometric methods .

Darstellung

synthetischeHydroxylamine sulfate may be prepared by mixing stoichiometric amountsof hydroxylamine and sulfuric acid. It also may be prepared by electrolytical-ly reducing an aqueous solution of ammonium sulfate.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

EthanolAmmoniumhydrogensulfitButanonoximSchwefeldioxidButanonAcetonoximAmmoniumsulfatSchwefelsure

Nachgelagerte Produkte

O-Ethylhydroxylaminhydrochlorid3-(4-NITRO-PHENYL)-ISOXAZOL-5-YLAMINE3-TERT-BUTYLISOXAZOL-5-AMINE

Zugehörige Reaktionen

198
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Reaktionsgleichung von HRID 127716
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Reaktionsgleichung von HRID 127717
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Wasserlöslichkeit
329 g/L · 329 g/L (20 ºC)
Merck
14 · 14,4828
Stabilität
Stable, but may be an explosion hazard - do not heat. May decompose explosively in the presence of alkalies. Air sensitive. Hygroscopic. Incompatible with copper, copper alloys, strong oxidising agents, strong bases, nitrites.
Kosmetik-Inhaltsstoffe Funktionen
ANTIOXIDANT
InChI
1S/2H3NO.H2O4S/c2*1-2;1-5(2,3)4/h2*2H,1H2;(H2,1,2,3,4)
InChIKey
VRXOQUOGDYKXFA-UHFFFAOYSA-N
SMILES
NO.NO.OS(O)(=O)=O
LogP
-1.031 · -1.031 (est)
CAS Datenbank
10039 · 10039-54-0(CAS DataBase Reference)
EPA chemische Informationen
Hydroxylamine sulfate (2:1) (10039-54-0)
Safe StorageSeparated from strong bases. Store in an area without drain or sewer access.
Spillage Disposal · 1 Eintrag

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. Carefully collect remainder. Then store and dispose of according to local regulations. Do NOT let this chemical enter the environment.

Eye PreventionWear safety goggles or eye protection in combination with breathing protection.
Fire PreventionNO open flames.
Inhalation RiskA harmful concentration of airborne particles can be reached quickly when dispersed.
Skin PreventionProtective gloves.
Exposure PreventionPREVENT DISPERSION OF DUST!
Ingestion PreventionDo not eat, drink, or smoke during work.
Inhalation PreventionUse ventilation, local exhaust or breathing protection.
Effects of Long Term ExposureRepeated or prolonged contact may cause skin sensitization.

Toxikologische Informationen

Exposure RoutesThe substance can be absorbed into the body by inhalation of its aerosol.
Signs and Symptoms · 4 Einträge

See Ingestion.

Redness. Pain.

Redness.

Blue lips, fingernails and skin. Confusion. Dizziness. Headache. Nausea.

ICSC Environmental DataThe substance is very toxic to aquatic organisms. It is strongly advised not to let the chemical enter into the environment.

Sicherheitsdaten

F
21
wgk
3
tsca
TSCA listed
ridadr
UN 2865
hs_code
28251000
RTECS-Nr.
NC5425000
risk_code
22-36/38-43-48/22-50-40-21/22-2
Toxizität
LD50 orally in Rabbit: 842 mg/kg LD50 dermal Rabbit 1500 - 2000 mg/kg
hazard_code
Xn,N,E
safety_code
22-24-37-61-36/37
hazard_class
8
packing_group
III
Speicherklasse
4.1A - Other explosive hazardous materials
Hazard Classifications
Acute Tox. 4 DermalAcute Tox. 4 OralAquatic Acute 1Carc. 2Eye Irrit. 2Met. Corr. 1Skin Irrit. 2Skin Sens. 1STOT RE 2 Oral
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