Methylphenoxyacetat

Methyl phenoxyacetate

HCID 16365CAS 2065-23-8
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Grundinformationen

Standard-SMILES
COC(=O)COc1ccccc1
InChIKey
BZCKRPHEZOHHBK-UHFFFAOYSA-N
Summenformel
C9H10O3
Durchschnittliche Molmasse
166,17 g/mol
Monoisotopische Masse
166,06299418

Namen und Bezeichner

Bevorzugter Name
Methyl phenoxyacetate
IUPAC
methyl 2-phenoxyacetate
Lokaler Name
Methylphenoxyacetat
Englischer Name
Methyl phenoxyacetate
Summenformel
C9H10O3
Molmasse
166.17

Namen und Synonyme

methyl 2-phenoxyacetateMETHYL PHENOXYACETATE2065-23-8Phenoxyacetic acid methyl esterAcetic acid, phenoxy-, methyl esterAcetic acid, 2-phenoxy-, methyl esterJD9OF3328OEINECS 218-176-4NSC 32414NSC-32414AI3-04318DTXSID2062161
Weitere Namen anzeigen
Methyl phenoxylateMethyl phenoxyacetatPHENOXY METHYL ACETATEMethylPhenoxyacetate>Methyl phenoxyacetate,99%Phenoxyacetic acid methylMethyl（ethyl）phenoxyacetatephenoxy-aceticacimethylester
RefChem:818034DTXCID9036359218-176-4InChI=1/C9H10O3/c1-11-9(10)7-12-8-5-3-2-4-6-8/h2-6H,7H2,1HMFCD00010227METHYLPHENOXYACETATEUNII-JD9OF3328OMethyl phenoxy acetate

Datenbank-Bezeichner

CAS
2065-23-8
PubChem CID
16365
DTXSID
DTXSID2062161
UNII
JD9OF3328O
EC Number
218-176-4
Nikkaji
J80.384G

Eigenschaften

Berechnete Struktureigenschaften

XLogP
1,4
Polarare Oberfläche (TPSA)
35,5 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
3
Frei drehbare Bindungen
4
Schwere Atome
12

Experimentelle und physikochemische Eigenschaften

SpringerMaterials PropertiesChemical shift
LogP1.41

Physikochemische Eigenschaften

Schmelzpunkt
245 °C · 245 °C
Siedepunkt
243 °C · 243 °C (lit.)
Dichte
1.149 g/mL · 1.149 g/mL at 25 °C (lit.)
Brechungsindex
20 · n20/D 1.514(lit.)
Flammpunkt
230 °F · >230 °F
storage temp.
Sealed in dry,Room Temperature

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Warning

H315 (98.9%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 95 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 3 Einträge

Chemical: Acetic acid, phenoxy-, methyl ester

Status: Active Update: 13-03-2017 https://echa.europa.eu/registration-dossier/-/registered-dossier/19264

Acetic acid, phenoxy-, methyl ester: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesSkin Irrit. 2 (98.9%)

Sicherheitsdaten

wgk
3
tsca
TSCA listed
hs_code
29189900
safety_code
24/25
Speicherklasse
12 - Non Combustible Liquids

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing InformationAcetic acid, 2-phenoxy-, methyl ester: INACTIVE

Anwendungen

VerwendenMethyl phenoxyacetate (MPOA) was used as an acylating agent in the synthesis of loracarbef, a carbacephalosporin antibiotic.

Darstellung · 1 Eintrag

synthetischesynthesis of methyl phenoxyacetate: methyl bromoacetate (10 mL, 105.6 mmol) and phenol (9.9380 g, 105.6 mmol) were dissolved in 250 mL of acetone; K2CO3 (21.89 g, 158 mmol) and KI (5 g, 30 mmol) were added and the mixture heated to reflux with stirring overnight. The mixture was filtered and the resultant solution concentrated in vacuo. Deionized water (200 mL) was added. The reaction mixture was extracted with 50 mL ethyl acetate three times. The combined ethyl acetate layers were washed with brine, dried over MgSO4, and filtered. All ethyl acetate was removed in vacuo, resulting in a slightly yellow liquid (80% yield).

Vor- und nachgelagerte Produkte

Anbieter50 Anbieter

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
山东旭晨化工科技有限公司0533-15715337262 15715337262 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]
毕佳索（上海毕得医药科技股份有限公司）400-6005915 · [email protected]

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