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Indiumtribromid

indium(III)bromide

HCID 167051
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Grundinformationen

CAS
13465-09-3
Standard-SMILES
[Br-].[Br-].[Br-].[In+3]
InChIKey
JKNHZOAONLKYQL-UHFFFAOYSA-K
Summenformel
Br3In
Durchschnittliche Molmasse
354,53 g/mol

Überblick

Indium(I) bromide is a chemical compound of indium and bromine. It has been used in the sulfur lamp and in organic chemistry. Bromine is a halogen element with the symbol Br and atomic number 35. Diatomic bromine does not occur naturally, but bromine salts can be found in crustal rock. (L625, L652)

Namen und Bezeichner

Bevorzugter Name
indium(III)bromide
IUPAC
indium(3+) tribromide
Lokaler Name
Indiumtribromid
Englischer Name
INDIUM(III) BROMIDE
Summenformel
Br3In
Molmasse
354.53

Namen und Synonyme

indium(III)bromideindium(3+);tribromideBr3InSCHEMBL20442INDIUM TRIBROMIDE [MI]EINECS 238-172-6AKOS025294346Indium(III) bromide, trace metals gradeNS00086611D78211F050479F870585
Weitere Namen anzeigen
InBr3INDIUM TRIBROMIDEINDIUM BROMIDETribromoindiumIndium(Ⅲ) bromideINDIUM(III) BROMIDEindiumbromide(inbr3)Indium(III) tribromideIndium bromide (InBr3)III)Indium(III bromide

Datenbank-Bezeichner

CAS
13465-09-3、14280-53-6
PubChem CID
167051
UNII
0099V88160
Nikkaji
J43.826J

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
3
Frei drehbare Bindungen
0
Schwere Atome
4
Formalladung
0
Komplexität
0

Physikochemische Eigenschaften

Schmelzpunkt
220 °C · 220 °C(lit.)
Siedepunkt
656 °C · 656 °C(lit.)
Dichte
4.96 g/mL · 4.96 g/mL at 25 °C(lit.)
Dampfdichte
1 · >1 (vs air)
storage temp.
Inert atmosphere,Room Temperature
Aggregatzustand
Crystalline Powder
Farbe
White to yellow
Wichte
4.74 · 4.74
Wasserlöslichkeit
Soluble in water.
Stabilität
hygroscopic
InChI
InChI=1S/3BrH.In/h3*1H;/q;;;+3/p-3
InChIKey
JKNHZOAONLKYQL-UHFFFAOYSA-K
SMILES
[In](Br)(Br)Br
EPA chemische Informationen
Indium bromide (InBr3) (13465-09-3)

Sicherheit und Regulatorisches

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Toxikologische Informationen

Treatment · 1 Eintrag

EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration.

Health Effects · 1 Eintrag

Bromine vapour causes irritation and direct damage to the mucous membranes. Elemental bromine also burns the skin. The bromide ion is a central nervous system depressant and chronic exposure produces neuronal effects. This is called bromism and can result in central reactions reaching from somnolence to coma, cachexia, exicosis, loss of reflexes or pathologic reflexes, clonic seizures, tremor, ataxia, loss of neural sensitivity, paresis, papillar edema of the eyes, abnormal speech, cerebral edema, delirium, aggressiveness, and psychoses. (L625, L626, L627)

Exposure RoutesOral (L626) ; inhalation (L626) ; dermal (L626)
Toxicity Summary · 1 Eintrag

Bromine is a powerful oxidizing agent and is able to release oxygen free radicals from the water in mucous membranes. These free radicals are also potent oxidizers and produce tissue damage. In additon, the formation of hydrobromic and bromic acids will result in secondary irritation. The bromide ion is also known to affect the central nervous system, causing bromism. This is believed to be a result of bromide ions substituting for chloride ions in the in actions of neurotransmitters and transport systems, thus affecting numerous synaptic processes. (L626, L627, A543)

Signs and Symptoms · 1 Eintrag

Bromine vapour causes irritation and direct damage to the mucous membranes. Symptoms include lacrimation, rhinorrhoea, eye irritation with mucous secretions from the oropharyngeal and upper airways, coughing, dyspnoea, choking, wheezing, epistaxis, and headache. The bromide ion is a central nervous system depressant producing ataxia, slurred speech, tremor, nausea, vomiting, lethargy, dizziness, visual disturbances, unsteadiness, headaches, impaired memory and concentration, disorientation and hallucinations. This is called bromism. (L626, L627)

Chemie und Industrie

Pharmakologische Informationen

Metabolism/Metabolites · 1 Eintrag

Bromine is mainly absorbed via inhalation, but may also enter the body through dermal contact. Bromine salts can be ingested. Due to its reactivity, bromine quickly forms bromide and may be deposited in the tissues, displacing other halogens. (L626)

Verwendung und Herstellung

UsesIndium(I) bromide has been used in the sulfur lamp and in organic chemistry. (L652)
Anwendungen · 1 Eintrag

Verwenden"Indium(III) bromide is used in organic synthesis as a water tolerant Lewis acid.It efficiently catalyzes the three-component coupling of β-keto esters, aldehydes and urea (or thiourea) to afford the corresponding dihydropyrimidinones. It is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells."

Darstellung · 1 Eintrag

synthetischeAccording to Thiel, metallic In is heated in a fast air-free stream of CO2, which is saturated with Br2 vapor by passage through a wash bottle containing Br2 (the bottle should be placed in a warm water bath). A melt of InBr and InBr3 forms first. This melt is brown at first, but gradually becomes lighter. Finally it turns to solid InBr3. The latter can be readily sublimed to form lustrous crystalline spangles.

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Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).

Sicherheitsdaten

wgk
3
tsca
TSCA listed
ridadr
UN3260
hs_code
28275900
risk_code
36/37/38
hazard_code
Xi
safety_code
26-36
hazard_class
8
packing_group
III
Speicherklasse
11 - Combustible Solids
Hazard Classifications
Eye Irrit. 2Skin Irrit. 2STOT SE 3
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