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Antimontribromid
Tribromostibine · tribromo-stibin · tribromostibane · ANTIMONY BROMIDE · tribromo-Stibine · Antimonousbromide · Stibine, tribromo- · ANTIMONY TRIBROMIDE

Identifikatoren & physikalische Daten
| CAS No. | 7789-61-9 |
|---|---|
| Summenformel | Br3Sb |
| Durchschnittliche Molmasse | 361,47 g/mol |
| Monoisotopische Masse | 357,658827 g/mol |
| SMILES | [Br][Sb]([Br])[Br] |
| InChIKey | RPJGYLSSECYURW-UHFFFAOYSA-K |
| PubChem CID | 24615 |
| EC No. | 232-179-8 |
| DTXSID | DTXSID6064870 |
| Lokaler Name | Antimontribromid |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 0 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 0 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 4 |
| Formalladung | 0 |
| Komplexität | 8 |
| Stoffklassen | Metals -> Metalloid Compounds (Antimony)Corrosives |
| Dichte | 4.148 at 73.4 °F (USCG, 1999) - Denser than waterwill sink4.148 at 23 °C/23 °C4.15 g/mL at 25 °C(lit.) |
| Color/Form | Yellow orthorhombic crystalsOrthorhombic, bipyramidal needlesYellow crystalline massYellow or white, deliquescent, crystalline mass becoming amber yellow when fusedColorless, crystalline solid having a pyramidal dimorphic molecular structure. |
| Löslichkeit | Reacts with waterSoluble in dilute hydrochloric acid, hydrobromic acid, carbon disulfide, acetone, benzene, chloroformSoluble in acetone, benzene, chloroformSoluble in ammoniaSoluble in dilute hydrochloric acid, hydrobromic acid, carbon disulfide, alcohol, acetone, ammonia, benzene, chloroform.decomposed by H2Osoluble dilute HCl, HBr [HAW93] [MER06] |
| Siedepunkt | 536 °F at 760 mmHg (USCG, 1999)288 °C280 °C |
| Decomposition | Decomposed by light, water, alcohol. |
| Schmelzpunkt | 205.88 °F (USCG, 1999)97 °C |
| Dampfdruck | 1 mm Hg at 93.9 °C1 mm Hg ( 94 °C) |
| Brechungsindex | Index of refraction: 1.74 |
| Heat of Vaporization | 53.2 kJ/mol at 560 °C |
| Physical Description | Antimony tribromide is a yellow crystalline solid, which is sometimes shipped as a solution in hydrobromic acid. It is decomposed by water giving an antimony oxide and hydrobromic acid. It is corrosive to tissue. It is used to make other antimony compounds, in chemical analysis, and in dyeing.Yellow deliquescent solid[Hawley] White powder[MSDSonline] |
| Stability/Shelf Life | Stable under recommended storage conditions. |
| Flammpunkt | 280°C |
| Aggregatzustand | Powder |
| Wichte | 4.15 |
| Farbe | White |
| Spezifische Wärmekapazität | Cp(gas): 0.22 J/(g·K), at 25℃ |
| Merck | 14,706 |
| Dielektrizitätskonstante | 20.899999999999999 |
| CAS Datenbank | 7789-61-9(CAS DataBase Reference) |
| EPA chemische Informationen | Antimony tribromide (7789-61-9) |
Sicherheit & Vorschriften
| GHS-Einstufung | WarningH302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]P261, P264, P270, P271, P273, P301+P317, P304+P340, P317, P330, P391, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 46 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.H302: Harmful if swallowed [Warning Acute toxicity, oral] |
|---|---|
| Regulatorische Informationen | The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| DOT-Kennzeichnung | Poison |
| Brandgefahren | Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: |
| Gesundheitsgefahren | INHALATION: Inflammation of mucous membranes of nose and throat. SKIN: Irritation and eczematous eruption. INGESTION: Gastro intestinal upset, vomiting, diarrhea. Nervous complaints such as irritability, sleeplessness, fatigue, muscular and neurologic pain. (USCG, 1999) |
| Gefahrenübersicht | A corrosive substance that can cause injury to the skin, eyes, and respiratory tractCan cause pulmonary edema[HSDB] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract[MSDSonline] See Antimony and linked occupational diseases. |
| Reaktive Gruppe | Acids, Strong Non-oxidizing |
| Reactivity Alerts | Water-Reactive |
| OSHA Standards | Permissible Exposure Limit: Table Z-1 8-Hour Time Weighted Avg: 0.5 mg/cu m. /Antimony and compounds (as Sb)/ |
| Reactivity Profile | ANTIMONY TRIBROMIDE is a strong oxidizing agent, and it is slowly hydrolyzed to generate hydrobromic acid and antimony oxides. |
| Luftstandards | Listed as a hazardous air pollutant (HAP) generally known or suspected to cause serious health problems. The Clean Air Act, as amended in 1990, directs EPA to set standards requiring major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed pollutants. Antimony compounds are included on this list. /Antimony Componds/ |
Anwendungen & Verwendung
Verwenden
Analytical chemistry, mordant, manufacturing antimony salts.