(Ethylenbis(nitrilomethylidyn)-2,2'-diphenolato)cobalt(II)

Salcomine

HCID 26517CAS 14167-18-1

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Grundinformationen

Standard-SMILES: [Co+2].[O-]c1ccccc1C=NCCN=Cc1ccccc1[O-]
InChIKey: NPAQSKHBTMUERN-UHFFFAOYSA-L
Summenformel: C16H14CoN2O2
Durchschnittliche Molmasse: 325,23 g/mol
Monoisotopische Masse: 325,038721

Namen und Bezeichner

Bevorzugter Name: Salcomine
IUPAC: cobalt(2+);2-[2-[(2-oxidophenyl)methylideneamino]ethyliminomethyl]phenolate
Lokaler Name: (Ethylenbis(nitrilomethylidyn)-2,2'-diphenolato)cobalt(II)
Englischer Name: SALCOMINE
Summenformel: C16H14CoN2O2
Molmasse: 325.23

Namen und Synonyme

14167-18-1SALCOMINESalcomincobalt(2+);2-[2-[(2-oxidophenyl)methylideneamino]ethyliminomethyl]phenolateMFCD00000009Salicylaldehyde ethylenediimine cobalt(N,N'-Bis(salicylidene)ethylenediamine)cobalt(II)Bis(salicylaldehyde)ethylenediimine cobalt(II)(N,N'-Ethylenebis(salicylaldehyde iminato))cobalt(II)(Ethylenebis(nitrilomethylidyne)-2,2'-diphenolato)cobalt(II)Cobalt, N,N'-ethylenebis(salicylideneiminato)-N,N-Ethylenebis(salicylideneiminato)cobalt(II)

Weitere Namen anzeigen

Co(salen)SALEN-COCO(SALEN)2Cobalt salen[N,N'-Bis(salicylidene)ethane-1,2-diaminato]cobalt(II)o’)-o(sp-4-2)-

N,N'-Bis(salicylidene)ethylenediiminocobalt(II)N2O9115YTKNSC32965NSC-32965C16H14CoN2O2N,N'-Bis(salicylidene)ethylenediaminocobalt(II)SALCOMINE [HSDB]SCHEMBL510827

Datenbank-Bezeichner

CAS: 14167-18-1
PubChem CID: 26517
UNII: N2O9115YTK

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 70,8 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 4
Frei drehbare Bindungen: 5
Schwere Atome: 21
Formalladung: 0
Komplexität: 298

Physikochemische Eigenschaften

Schmelzpunkt: 300 °C · >300 °C
storage temp.: Inert atmosphere,Room Temperature
Aggregatzustand: Powder
Farbe: Orange to Amber to Dark red
Wasserlöslichkeit: Insoluble in water. Soluble in benzene, chloroform, and pyridine.
Stabilität: Stable. Incompatible with strong acids, strong oxidizing agents.
InChI: InChI=1S/C16H16N2O2.Co/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20;/h1-8,11-12,19-20H,9-10H2;/q;+2/p-2/b17-11+,18-12+;
InChIKey: NPAQSKHBTMUERN-OYJDLGDISA-L
SMILES: C12=CC=CC=C1C=NCCN=CC1=CC=CC=C1O[Co]O2 |t:7,11|
EPA chemische Informationen: Salcomine (14167-18-1)

Sicherheit und Regulatorisches

Sicherheitsdaten

F: 10
wgk: 2
tsca: TSCA listed
hs_code: 29349990
RTECS-Nr.: GG0590000
risk_code: 36/37/38
Toxizität: mouse,LCLo,inhalation,390mg/m3/5.5H (390mg/m3),LUNGS, THORAX, OR RESPIRATION: STRUCTURAL OR FUNCTIONAL CHANGE IN TRACHEA OR BRONCHILUNGS, THORAX, OR RESPIRATION: OTHER CHANGESLUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA,Aerospace Medical Research Laboratory Report. Vol. TR-74-78, Pg. 1974,
hazard_code: Xi
safety_code: 26-36
Speicherklasse: 11 - Combustible Solids
Giftige Stoffe Daten: 14167-18-1(Hazardous Substances Data)
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3

Chemie und Industrie

Anwendungen

VerwendenSalcomine catalyzes the oxidation of 2,6-disubstituted phenols by dioxygen. Experimental inhibitor of human cytμloviris proteinase activity. Metal complex dyes used as redox catalysts.