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(Ethylenbis(nitrilomethylidyn)-2,2'-diphenolato)cobalt(II)
Co(salen) · SALEN-CO · Salcomin · CO(SALEN)2 · Cobalt salen · [N,N'-Bis(salicylidene)ethane-1,2-diaminato]cobalt(II) · o’)-o · Nsc32965
Identifikatoren & physikalische Daten
| CAS No. | 14167-18-1 |
|---|---|
| Summenformel | C16H14CoN2O2 |
| Durchschnittliche Molmasse | 325,23 g/mol |
| Monoisotopische Masse | 325,038721 g/mol |
| SMILES | [Co+2].[O-]c1ccccc1C=NCCN=Cc1ccccc1[O-] |
| InChIKey | NPAQSKHBTMUERN-UHFFFAOYSA-L |
| PubChem CID | 26517 |
| Lokaler Name | (Ethylenbis(nitrilomethylidyn)-2,2'-diphenolato)cobalt(II) |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 70,8 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 4 |
| Frei drehbare Bindungen | 5 |
| Schwere Atome | 21 |
| Formalladung | 0 |
| Komplexität | 298 |
| Schmelzpunkt | >300 °C |
| Lagerbedingungen | Inert atmosphere,Room Temperature |
| Aggregatzustand | Powder |
| Farbe | Orange to Amber to Dark red |
| Löslichkeit | Insoluble in water. Soluble in benzene, chloroform, and pyridine. |
| Stabilität | Stable. Incompatible with strong acids, strong oxidizing agents. |
| InChI | InChI=1S/C16H16N2O2.Co/c19-15-7-3-1-5-13(15)11-17-9-10-18-12-14-6-2-4-8-16(14)20/h1-8,11-12,19-20H,9-10H2/q+2/p-2/b17-11+,18-12+ |
| InChIKey | NPAQSKHBTMUERN-OYJDLGDISA-L |
| SMILES | C12=CC=CC=C1C=NCCN=CC1=CC=CC=C1O[Co]O2 |t:7,11| |
| EPA chemische Informationen | Salcomine (14167-18-1) |
Sicherheit & Vorschriften
| F | 10 |
|---|---|
| Wassergefährdungsklasse (WGK) | 2 |
| TSCA-Inventar-Status | TSCA listed |
| Zollcode | 29349990 |
| RTECS-Nr. | GG0590000 |
| R-Sätze (R) | 36/37/38 |
| Toxizität | mouse,LCLo,inhalation,390mg/m3/5.5H (390mg/m3),LUNGS, THORAX, OR RESPIRATION: STRUCTURAL OR FUNCTIONAL CHANGE IN TRACHEA OR BRONCHILUNGS, THORAX, OR RESPIRATION: OTHER CHANGESLUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMA,Aerospace Medical Research Laboratory Report. Vol. TR-74-78, Pg. 1974, |
| Gefahrensymbole | Xi |
| Sicherheitshinweise (S) | 26-36 |
| Lagerklasse | 11 - Combustible Solids |
| Gefahrstoffdaten | 14167-18-1(Hazardous Substances Data) |
| Gefahrenklasse | Eye Irrit. 2Skin Irrit. 2STOT SE 3 |
Anwendungen & Verwendung
Verwenden
Salcomine catalyzes the oxidation of 2,6-disubstituted phenols by dioxygen. Experimental inhibitor of human cytμloviris proteinase activity. Metal complex dyes used as redox catalysts.