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Phoxim (ISO)
Foxim · PHOXIM · Phoxin · b77488 · VOLATON · oms1170 · Phoxime · Sebacil
Identifikatoren & physikalische Daten
| CAS No. | 14816-18-3 |
|---|---|
| Summenformel | C12H15N2O3PS |
| Durchschnittliche Molmasse | 298,3 g/mol |
| Monoisotopische Masse | 298,05410052 g/mol |
| SMILES | CCOP(=S)(OCC)ON=C(C#N)c1ccccc1 |
| InChIKey | ATROHALUCMTWTB-UHFFFAOYSA-N |
| PubChem CID | 26927 |
| ChEMBL | CHEMBL1906626 |
| EC No. | 238-887-3 |
| DTXSID | DTXSID8034324 |
| Lokaler Name | Phoxim (ISO) |
Chemische & physikalische Eigenschaften
| XLogP | 4,4 |
|---|---|
| Polarare Oberfläche (TPSA) | 95,9 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 6 |
| Frei drehbare Bindungen | 7 |
| Schwere Atome | 19 |
| Formalladung | 0 |
| Komplexität | 389 |
| Collision Cross Section | 165.7 Ų [M-H]- [CCS Type: DTBuffer gas: N2Ionization: ESI-Dataset: TOXCASTSource Identifier: DTXSID8034324] |
| Schmelzpunkt | 5.55°C |
| Siedepunkt | bp0.01 102° |
| Dichte | d420 1.176 |
| Dampfdruck | 2.1×10-3 Pa (20 °C) |
| Brechungsindex | nD20 1.5405 |
| Lagerbedingungen | 0-6°C |
| Löslichkeit | Acetonitrile (Slightly), Chloroform (Slightly), Methanol (Slightly)1.5 mg l-1 (20 °C) |
| Aggregatzustand | liquid |
| Farbe | Colorless to light yellow |
| Henry-Konstante | 5.0×101 mol/(m3Pa) at 25℃, Ebert et al. (2023) |
| Stabilität | Hygroscopic, Moisture Sensitive |
| InChIKey | ATROHALUCMTWTB-WYMLVPIESA-N |
| CAS Datenbank | 14816-18-3(CAS DataBase Reference) |
| NIST chemische Informationen | Phoxim(14816-18-3) |
| EPA chemische Informationen | Phoxim (14816-18-3) |
Sicherheit & Vorschriften
| GHS-Einstufung | WarningH302: Harmful if swallowed [Warning Acute toxicity, oral]H317: May cause an allergic skin reaction [Warning Sensitization, Skin]H361f ***: Suspected of damaging fertility [Warning Reproductive toxicity]H400: Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]H410: Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]P203, P261, P264, P270, P272, P273, P280, P301+P317, P302+P352, P318, P321, P330, P333+P317, P362+P364, P391, P405, and P501 (click each P-code to see the statement)Danger |
|---|---|
| Weitere Sicherheitsinformationen | IMAP assessments - 3,5-Dioxa-6-aza-4-phosphaoct-6-ene-8-nitrile, 4-ethoxy-7-phenyl-, 4-sulfide: Human health tier I assessmentIMAP assessments - 3,5-Dioxa-6-aza-4-phosphaoct-6-ene-8-nitrile, 4-ethoxy-7-phenyl-, 4-sulfide: Environment tier I assessment |
| Hazard Classes and Categories | Acute Tox. 3 (33.6%)Acute Tox. 4 (66.4%)Acute Tox. 3 (67.3%)Skin Sens. 1 (97.3%)Acute Tox. 2 (34.5%)Repr. 2 (96.5%)Aquatic Acute 1 (100%)Aquatic Chronic 1 (100%)Reproductive toxicity - category 2Acute toxicity - category 4Skin sensitisation - category 1Hazardous to the aquatic environment (acute) - category 1Hazardous to the aquatic environment (chronic) - category 1Acute Tox. 4 *Aquatic Chronic 1 |
| Acute Toxicity Link | Chemical: PHOXIM |
| Wassergefährdungsklasse (WGK) | 3 |
| UN-Transportnummer | UN 2810 |
| Zollcode | 29269090 |
| RTECS-Nr. | MD4740000 |
| R-Sätze (R) |
Anwendungen & Verwendung
Beschreibung
Phoxim is a light yellow liquid, Solubility in water is 1.5 mg/L (20 C). It is readily soluble in most organic solvents and slightly in aliphatic hydrocarbons. Log Kow = 3.38. It is relatively slowly hydrolyzed in aqueous media; DT50 (22 C) at pH 4, 7, and 9 is 26.7, 7.2, and 3.1 d, respectively.
Verwenden
Phoxim is used to control stored product insect pests in silos and barns. It is also used to control household insects such as ants and other public health pests. Agricultural targets include caterpillars and soil insects in maize, vegetables, cotton and potatoes.